π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched “on–off–on” electrochromic system with two near-infrared fluorescent outputs

Nathan L. Bill; Jong Min Lim; Christina M. Davis; Steffen Bähring; Jan O. Jeppesen; Dongho Kim; Jonathan L. Sessler

doi:10.1039/c4cc02567a

π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched “on–off–on” electrochromic system with two near-infrared fluorescent outputs

Nathan L. Bill
, Jong Min Lim
, Christina M. Davis
, Steffen Bähring
, Jan O. Jeppesen
, Dongho Kim
, Jonathan L. Sessler

University of Texas at Austin
University of Southern Denmark
Yonsei University

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched “on–off–on” emissive system.

Original language	English
Pages (from-to)	6758-6761
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	51
DOIs	https://doi.org/10.1039/c4cc02567a
State	Published - 29 May 2014

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title = "π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched “on–off–on” electrochromic system with two near-infrared fluorescent outputs",

abstract = "A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched “on–off–on” emissive system.",

author = "Bill, \{Nathan L.\} and Lim, \{Jong Min\} and Davis, \{Christina M.\} and Steffen B{\"a}hring and Jeppesen, \{Jan O.\} and Dongho Kim and Sessler, \{Jonathan L.\}",

year = "2014",

month = may,

day = "29",

doi = "10.1039/c4cc02567a",

language = "English",

volume = "50",

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journal = "Chemical Communications",

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T1 - π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY)

T2 - A redox switched “on–off–on” electrochromic system with two near-infrared fluorescent outputs

AU - Bill, Nathan L.

AU - Lim, Jong Min

AU - Davis, Christina M.

AU - Bähring, Steffen

AU - Jeppesen, Jan O.

AU - Kim, Dongho

AU - Sessler, Jonathan L.

PY - 2014/5/29

Y1 - 2014/5/29

N2 - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched “on–off–on” emissive system.

AB - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched “on–off–on” emissive system.

UR - https://www.scopus.com/pages/publications/84901755282

U2 - 10.1039/c4cc02567a

DO - 10.1039/c4cc02567a

M3 - Article

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AN - SCOPUS:84901755282

SN - 1359-7345

VL - 50

SP - 6758

EP - 6761

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched “on–off–on” electrochromic system with two near-infrared fluorescent outputs

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