{3-[Bis(2-pyridylmethyl-kN)amino-kN]-propanol}bis(nitrato-kO)copper(II)

Sankara Rao Rowthu; Jong Won Shin; Yu Rim Seo; Kil Sik Min

doi:10.1107/S1600536810051779

{3-[Bis(2-pyridylmethyl-kN)amino-kN]-propanol}bis(nitrato-kO)copper(II)

Sankara Rao Rowthu, Jong Won Shin, Yu Rim Seo, Kil Sik Min

Department of Chemical Science Education

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

In the title compound, [Cu(NO₃)₂(C₁₅H ₁₉N₃O)], the Cu^II ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O-H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes.

Original language	English
Pages (from-to)	m85
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	1
DOIs	https://doi.org/10.1107/S1600536810051779
State	Published - Jan 2011

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title = "\{3-[Bis(2-pyridylmethyl-kN)amino-kN]-propanol\}bis(nitrato-kO)copper(II)",

abstract = "In the title compound, [Cu(NO3)2(C15H 19N3O)], the CuII ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O-H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes.",

author = "Rowthu, \{Sankara Rao\} and Shin, \{Jong Won\} and Seo, \{Yu Rim\} and Min, \{Kil Sik\}",

year = "2011",

month = jan,

doi = "10.1107/S1600536810051779",

language = "English",

volume = "67",

pages = "m85",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - {3-[Bis(2-pyridylmethyl-kN)amino-kN]-propanol}bis(nitrato-kO)copper(II)

AU - Rowthu, Sankara Rao

AU - Shin, Jong Won

AU - Seo, Yu Rim

AU - Min, Kil Sik

PY - 2011/1

Y1 - 2011/1

N2 - In the title compound, [Cu(NO3)2(C15H 19N3O)], the CuII ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O-H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes.

AB - In the title compound, [Cu(NO3)2(C15H 19N3O)], the CuII ion is coordinated by the N atoms of the tetradentate 3-[bis(2-pyridylmethyl)amino]propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An intermolecular O-H⋯O hydrogen-bonding interaction between the free hydroxy group of the ligand and a nitrate O atom of an adjacent complex unit, gives a chain structure which extends across the (101) planes.

UR - https://www.scopus.com/pages/publications/78650743775

U2 - 10.1107/S1600536810051779

DO - 10.1107/S1600536810051779

M3 - Article

AN - SCOPUS:78650743775

SN - 1600-5368

VL - 67

SP - m85

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

{3-[Bis(2-pyridylmethyl-kN)amino-kN]-propanol}bis(nitrato-kO)copper(II)

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