A colorimetric chemosensor for the sequential detection of copper(II) and cysteine

Seul Ah Lee; Jae Jun Lee; Jong Won Shin; Kil Sik Min; Cheal Kim

doi:10.1016/j.dyepig.2015.01.020

A colorimetric chemosensor for the sequential detection of copper(II) and cysteine

Seul Ah Lee, Jae Jun Lee, Jong Won Shin, Kil Sik Min, Cheal Kim

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

103 Scopus citations

Abstract

A simple and easy-to-make colorimetric chemosensor 1 for the sequential detection of Cu²⁺ and cysteine was developed by combination of hydroxynaphthalene-2-carbaldehyde and diaminomaleonitrile. This sensor 1 exhibited an obvious color change from pale yellow to orange in the presence of Cu²⁺ in aqueous solution. Also, the resulting 1-Cu²⁺ complex sensed cysteine through naked-eye, showing recovery from 1-Cu²⁺ to 1, over other sulfur-containing amino acid and peptide. Moreover, the sensing ability of 1 for Cu²⁺ was supported by theoretical calculations.

Original language	English
Pages (from-to)	131-138
Number of pages	8
Journal	Dyes and Pigments
Volume	116
DOIs	https://doi.org/10.1016/j.dyepig.2015.01.020
State	Published - May 2015

Keywords

Colorimetric chemosensor
Copper
Cysteine
Sequential detection
Theoretical calculations

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10.1016/j.dyepig.2015.01.020

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title = "A colorimetric chemosensor for the sequential detection of copper(II) and cysteine",

abstract = "A simple and easy-to-make colorimetric chemosensor 1 for the sequential detection of Cu2+ and cysteine was developed by combination of hydroxynaphthalene-2-carbaldehyde and diaminomaleonitrile. This sensor 1 exhibited an obvious color change from pale yellow to orange in the presence of Cu2+ in aqueous solution. Also, the resulting 1-Cu2+ complex sensed cysteine through naked-eye, showing recovery from 1-Cu2+ to 1, over other sulfur-containing amino acid and peptide. Moreover, the sensing ability of 1 for Cu2+ was supported by theoretical calculations.",

keywords = "Colorimetric chemosensor, Copper, Cysteine, Sequential detection, Theoretical calculations",

author = "Lee, {Seul Ah} and Lee, {Jae Jun} and Shin, {Jong Won} and Min, {Kil Sik} and Cheal Kim",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd.",

year = "2015",

month = may,

doi = "10.1016/j.dyepig.2015.01.020",

language = "English",

volume = "116",

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journal = "Dyes and Pigments",

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T1 - A colorimetric chemosensor for the sequential detection of copper(II) and cysteine

AU - Lee, Seul Ah

AU - Lee, Jae Jun

AU - Shin, Jong Won

AU - Min, Kil Sik

AU - Kim, Cheal

PY - 2015/5

Y1 - 2015/5

N2 - A simple and easy-to-make colorimetric chemosensor 1 for the sequential detection of Cu2+ and cysteine was developed by combination of hydroxynaphthalene-2-carbaldehyde and diaminomaleonitrile. This sensor 1 exhibited an obvious color change from pale yellow to orange in the presence of Cu2+ in aqueous solution. Also, the resulting 1-Cu2+ complex sensed cysteine through naked-eye, showing recovery from 1-Cu2+ to 1, over other sulfur-containing amino acid and peptide. Moreover, the sensing ability of 1 for Cu2+ was supported by theoretical calculations.

AB - A simple and easy-to-make colorimetric chemosensor 1 for the sequential detection of Cu2+ and cysteine was developed by combination of hydroxynaphthalene-2-carbaldehyde and diaminomaleonitrile. This sensor 1 exhibited an obvious color change from pale yellow to orange in the presence of Cu2+ in aqueous solution. Also, the resulting 1-Cu2+ complex sensed cysteine through naked-eye, showing recovery from 1-Cu2+ to 1, over other sulfur-containing amino acid and peptide. Moreover, the sensing ability of 1 for Cu2+ was supported by theoretical calculations.

KW - Colorimetric chemosensor

KW - Copper

KW - Cysteine

KW - Sequential detection

KW - Theoretical calculations

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M3 - Article

AN - SCOPUS:84922447887

SN - 0143-7208

VL - 116

SP - 131

EP - 138

JO - Dyes and Pigments

JF - Dyes and Pigments

ER -

A colorimetric chemosensor for the sequential detection of copper(II) and cysteine

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Keywords

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