A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

Kil Sik Min; Krzysztof Swierczek; Antonio G. DiPasquale; Arnold L. Rheingold; William M. Reiff; Atta M. Arif; Joel S. Miller

doi:10.1039/b715271j

A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

Kil Sik Min, Krzysztof Swierczek, Antonio G. DiPasquale, Arnold L. Rheingold, William M. Reiff, Atta M. Arif, Joel S. Miller

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Dinuclear [(TPyA)Fe^II(THBQ^2-)Fe^II(TPyA)] (BF₄)₂ (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

Original language	English
Pages (from-to)	317-319
Number of pages	3
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/b715271j
State	Published - 2008

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Min, K. S., Swierczek, K., DiPasquale, A. G., Rheingold, A. L., Reiff, W. M., Arif, A. M., & Miller, J. S. (2008). A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. Chemical Communications, (3), 317-319. https://doi.org/10.1039/b715271j

@article{4519a9e703374be2b35cf388aa6018e8,

title = "A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange",

abstract = "Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.",

author = "Min, {Kil Sik} and Krzysztof Swierczek and DiPasquale, {Antonio G.} and Rheingold, {Arnold L.} and Reiff, {William M.} and Arif, {Atta M.} and Miller, {Joel S.}",

year = "2008",

doi = "10.1039/b715271j",

language = "English",

pages = "317--319",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "3",

}

Min, KS, Swierczek, K, DiPasquale, AG, Rheingold, AL, Reiff, WM, Arif, AM & Miller, JS 2008, 'A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange', Chemical Communications, no. 3, pp. 317-319. https://doi.org/10.1039/b715271j

A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. / Min, Kil Sik; Swierczek, Krzysztof; DiPasquale, Antonio G. et al.
In: Chemical Communications, No. 3, 2008, p. 317-319.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

AU - Min, Kil Sik

AU - Swierczek, Krzysztof

AU - DiPasquale, Antonio G.

AU - Rheingold, Arnold L.

AU - Reiff, William M.

AU - Arif, Atta M.

AU - Miller, Joel S.

PY - 2008

Y1 - 2008

N2 - Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

AB - Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

UR - http://www.scopus.com/inward/record.url?scp=37749002749&partnerID=8YFLogxK

U2 - 10.1039/b715271j

DO - 10.1039/b715271j

M3 - Article

AN - SCOPUS:37749002749

SN - 1359-7345

SP - 317

EP - 319

JO - Chemical Communications

JF - Chemical Communications

IS - 3