A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

Kil Sik Min; Krzysztof Swierczek; Antonio G. DiPasquale; Arnold L. Rheingold; William M. Reiff; Atta M. Arif; Joel S. Miller

doi:10.1039/b715271j

A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

Kil Sik Min
, Krzysztof Swierczek
, Antonio G. DiPasquale
, Arnold L. Rheingold
, William M. Reiff
, Atta M. Arif
, Joel S. Miller

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Dinuclear [(TPyA)Fe^II(THBQ^2-)Fe^II(TPyA)] (BF₄)₂ (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

Original language	English
Pages (from-to)	317-319
Number of pages	3
Journal	Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/b715271j
State	Published - 2008

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Min, K. S., Swierczek, K., DiPasquale, A. G., Rheingold, A. L., Reiff, W. M., Arif, A. M., & Miller, J. S. (2008). A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. Chemical Communications, (3), 317-319. https://doi.org/10.1039/b715271j

@article{4519a9e703374be2b35cf388aa6018e8,

title = "A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange",

abstract = "Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.",

author = "Min, \{Kil Sik\} and Krzysztof Swierczek and DiPasquale, \{Antonio G.\} and Rheingold, \{Arnold L.\} and Reiff, \{William M.\} and Arif, \{Atta M.\} and Miller, \{Joel S.\}",

year = "2008",

doi = "10.1039/b715271j",

language = "English",

pages = "317--319",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "3",

}

Min, KS, Swierczek, K, DiPasquale, AG, Rheingold, AL, Reiff, WM, Arif, AM & Miller, JS 2008, 'A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange', Chemical Communications, no. 3, pp. 317-319. https://doi.org/10.1039/b715271j

A dinuclear iron(II) complex, [(TPyA)Fe^II(THBQ ^2-)Fe^II(TPyA)](BF₄)₂ [TPyA = tris(2-pyridylmethyl)amine; THBQ^2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. / Min, Kil Sik; Swierczek, Krzysztof; DiPasquale, Antonio G. et al.
In: Chemical Communications, No. 3, 2008, p. 317-319.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

AU - Min, Kil Sik

AU - Swierczek, Krzysztof

AU - DiPasquale, Antonio G.

AU - Rheingold, Arnold L.

AU - Reiff, William M.

AU - Arif, Atta M.

AU - Miller, Joel S.

PY - 2008

Y1 - 2008

N2 - Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

AB - Dinuclear [(TPyA)FeII(THBQ2-)FeII(TPyA)] (BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and π-π interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature.

UR - https://www.scopus.com/pages/publications/37749002749

U2 - 10.1039/b715271j

DO - 10.1039/b715271j

M3 - Article

AN - SCOPUS:37749002749

SN - 1359-7345

SP - 317

EP - 319

JO - Chemical Communications

JF - Chemical Communications

IS - 3