A recyclable copper catalysis in quinoxaline synthesis from α-hydroxyketones and o-phenylenediamines

Chan Sik Cho; Wen Xiu Ren

doi:10.1016/j.jorganchem.2009.06.002

A recyclable copper catalysis in quinoxaline synthesis from α-hydroxyketones and o-phenylenediamines

Chan Sik Cho, Wen Xiu Ren

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Short survey › peer-review

31 Scopus citations

Abstract

o-Phenylenediamines react with α-hydroxyketones in toluene at 100 °C in the presence of a catalytic amount of a copper catalyst along with MS 4A under O₂ atmosphere to afford the corresponding quinoxalines in high yields. The catalytic system could be easily recovered and reused several times without any loss of catalytic activity.

Original language	English
Pages (from-to)	3215-3217
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	19
DOIs	https://doi.org/10.1016/j.jorganchem.2009.06.002
State	Published - 1 Sep 2009

Keywords

α-Hydroxyketones
o-Phenylenediamines
Oxidative cyclization
Quinoxalines
Recyclable copper catalyst

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10.1016/j.jorganchem.2009.06.002

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title = "A recyclable copper catalysis in quinoxaline synthesis from α-hydroxyketones and o-phenylenediamines",

abstract = "o-Phenylenediamines react with α-hydroxyketones in toluene at 100 °C in the presence of a catalytic amount of a copper catalyst along with MS 4A under O2 atmosphere to afford the corresponding quinoxalines in high yields. The catalytic system could be easily recovered and reused several times without any loss of catalytic activity.",

keywords = "α-Hydroxyketones, o-Phenylenediamines, Oxidative cyclization, Quinoxalines, Recyclable copper catalyst",

author = "Cho, {Chan Sik} and Ren, {Wen Xiu}",

year = "2009",

month = sep,

day = "1",

doi = "10.1016/j.jorganchem.2009.06.002",

language = "English",

volume = "694",

pages = "3215--3217",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - A recyclable copper catalysis in quinoxaline synthesis from α-hydroxyketones and o-phenylenediamines

AU - Cho, Chan Sik

AU - Ren, Wen Xiu

PY - 2009/9/1

Y1 - 2009/9/1

N2 - o-Phenylenediamines react with α-hydroxyketones in toluene at 100 °C in the presence of a catalytic amount of a copper catalyst along with MS 4A under O2 atmosphere to afford the corresponding quinoxalines in high yields. The catalytic system could be easily recovered and reused several times without any loss of catalytic activity.

AB - o-Phenylenediamines react with α-hydroxyketones in toluene at 100 °C in the presence of a catalytic amount of a copper catalyst along with MS 4A under O2 atmosphere to afford the corresponding quinoxalines in high yields. The catalytic system could be easily recovered and reused several times without any loss of catalytic activity.

KW - α-Hydroxyketones

KW - o-Phenylenediamines

KW - Oxidative cyclization

KW - Quinoxalines

KW - Recyclable copper catalyst

UR - http://www.scopus.com/inward/record.url?scp=68049143148&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2009.06.002

DO - 10.1016/j.jorganchem.2009.06.002

M3 - Short survey

AN - SCOPUS:68049143148

SN - 0022-328X

VL - 694

SP - 3215

EP - 3217

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 19

ER -

A recyclable copper catalysis in quinoxaline synthesis from α-hydroxyketones and o-phenylenediamines

Abstract

Keywords

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