A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

Son Long Ho; Il Chul Yoon; Chan Sik Cho; Heung Jin Choi

doi:10.1016/j.jorganchem.2015.05.040

A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

Son Long Ho
, Il Chul Yoon
, Chan Sik Cho
, Heung Jin Choi

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

β-Bromo-α,β-unsaturated carboxylic acids react with terminal alkynes in DMF in the presence of a catalytic amount of metal-organic framework MOF-199 along with a base under microwave irradiation to afford the corresponding alkylidenefuranones in good yields. The catalytic system could be easily recovered and reused 5 times without any loss of catalytic activity.

Original language	English
Pages (from-to)	13-17
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	791
DOIs	https://doi.org/10.1016/j.jorganchem.2015.05.040
State	Published - 30 May 2015

Keywords

Heterocycles
MOF-199
Sonogashira coupling
Terminal alkynes
β-Bromo-α,β-unsaturated carboxylic acids

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10.1016/j.jorganchem.2015.05.040

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@article{1c18008bb8fe4bb9aae32979e9221b78,

title = "A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones",

abstract = "β-Bromo-α,β-unsaturated carboxylic acids react with terminal alkynes in DMF in the presence of a catalytic amount of metal-organic framework MOF-199 along with a base under microwave irradiation to afford the corresponding alkylidenefuranones in good yields. The catalytic system could be easily recovered and reused 5 times without any loss of catalytic activity.",

keywords = "Heterocycles, MOF-199, Sonogashira coupling, Terminal alkynes, β-Bromo-α,β-unsaturated carboxylic acids",

author = "Ho, \{Son Long\} and Yoon, \{Il Chul\} and Cho, \{Chan Sik\} and Choi, \{Heung Jin\}",

note = "Publisher Copyright: {\textcopyright} 2015 Published by Elsevier B.V.",

year = "2015",

month = may,

day = "30",

doi = "10.1016/j.jorganchem.2015.05.040",

language = "English",

volume = "791",

pages = "13--17",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones. / Ho, Son Long; Yoon, Il Chul; Cho, Chan Sik et al.
In: Journal of Organometallic Chemistry, Vol. 791, 30.05.2015, p. 13-17.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

AU - Ho, Son Long

AU - Yoon, Il Chul

AU - Cho, Chan Sik

AU - Choi, Heung Jin

PY - 2015/5/30

Y1 - 2015/5/30

N2 - β-Bromo-α,β-unsaturated carboxylic acids react with terminal alkynes in DMF in the presence of a catalytic amount of metal-organic framework MOF-199 along with a base under microwave irradiation to afford the corresponding alkylidenefuranones in good yields. The catalytic system could be easily recovered and reused 5 times without any loss of catalytic activity.

AB - β-Bromo-α,β-unsaturated carboxylic acids react with terminal alkynes in DMF in the presence of a catalytic amount of metal-organic framework MOF-199 along with a base under microwave irradiation to afford the corresponding alkylidenefuranones in good yields. The catalytic system could be easily recovered and reused 5 times without any loss of catalytic activity.

KW - Heterocycles

KW - MOF-199

KW - Sonogashira coupling

KW - Terminal alkynes

KW - β-Bromo-α,β-unsaturated carboxylic acids

UR - https://www.scopus.com/pages/publications/84930225305

U2 - 10.1016/j.jorganchem.2015.05.040

DO - 10.1016/j.jorganchem.2015.05.040

M3 - Article

AN - SCOPUS:84930225305

SN - 0022-328X

VL - 791

SP - 13

EP - 17

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

A recyclable metal-organic framework MOF-199 catalyst in coupling and cyclization of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

Abstract

Keywords

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