Abstract
We present an elementary pedagogical derivation of the Brillouin-Wigner and the Rayleigh-Schrödinger perturbation theories with Epstein-Nesbet partitioning. A variant of the Brillouin-Wigner perturbation theory is also introduced, which can be easily extended to the quasi-degenerate case. A main advantage of the new theory is that the computing time required for obtaining the successive higher-order results is minimal after the third-order calculation. We illustrate the accuracy of the new perturbation theory for some simple model systems like the perturbed harmonic oscillator and the particle in a box.
Original language | English |
---|---|
Pages (from-to) | 3279-3283 |
Number of pages | 5 |
Journal | Bulletin of the Korean Chemical Society |
Volume | 34 |
Issue number | 11 |
DOIs | |
State | Published - 20 Nov 2013 |
Keywords
- Perturbation theory