Abstract
We present an elementary pedagogical derivation of the Brillouin-Wigner and the Rayleigh-Schrödinger perturbation theories with Epstein-Nesbet partitioning. A variant of the Brillouin-Wigner perturbation theory is also introduced, which can be easily extended to the quasi-degenerate case. A main advantage of the new theory is that the computing time required for obtaining the successive higher-order results is minimal after the third-order calculation. We illustrate the accuracy of the new perturbation theory for some simple model systems like the perturbed harmonic oscillator and the particle in a box.
| Original language | English |
|---|---|
| Pages (from-to) | 3279-3283 |
| Number of pages | 5 |
| Journal | Bulletin of the Korean Chemical Society |
| Volume | 34 |
| Issue number | 11 |
| DOIs | |
| State | Published - 20 Nov 2013 |
Keywords
- Perturbation theory
Fingerprint
Dive into the research topics of 'A variant of the brillouin-wigner perturbation theory with epstein-nesbet partitioning'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver