A versatile synthetic approach to grandisol monoterpene pheromone

Young Taek Han; Nam Jung Kim; Jong Wha Jung; Hwayoung Yun; Sujin Lee; Young Ger Suh

doi:10.1007/s12272-011-0904-7

A versatile synthetic approach to grandisol monoterpene pheromone

Young Taek Han, Nam Jung Kim, Jong Wha Jung, Hwayoung Yun, Sujin Lee, Young Ger Suh

Seoul National University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

Original language	English
Pages (from-to)	1437-1442
Number of pages	6
Journal	Archives of Pharmacal Research
Volume	34
Issue number	9
DOIs	https://doi.org/10.1007/s12272-011-0904-7
State	Published - Sep 2011

Keywords

Grandisol
Palladium
Pesticide
Pheromone
Synthesis

Access to Document

10.1007/s12272-011-0904-7

Cite this

@article{73029d70a72a4e21b54ba7fc34462ffd,

title = "A versatile synthetic approach to grandisol monoterpene pheromone",

abstract = "A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.",

keywords = "Grandisol, Palladium, Pesticide, Pheromone, Synthesis",

author = "Han, {Young Taek} and Kim, {Nam Jung} and Jung, {Jong Wha} and Hwayoung Yun and Sujin Lee and Suh, {Young Ger}",

year = "2011",

month = sep,

doi = "10.1007/s12272-011-0904-7",

language = "English",

volume = "34",

pages = "1437--1442",

journal = "Archives of Pharmacal Research",

issn = "0253-6269",

publisher = "Pharmaceutical Society of Korea",

number = "9",

}

TY - JOUR

T1 - A versatile synthetic approach to grandisol monoterpene pheromone

AU - Han, Young Taek

AU - Kim, Nam Jung

AU - Jung, Jong Wha

AU - Yun, Hwayoung

AU - Lee, Sujin

AU - Suh, Young Ger

PY - 2011/9

Y1 - 2011/9

N2 - A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

AB - A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

KW - Grandisol

KW - Palladium

KW - Pesticide

KW - Pheromone

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=80755159039&partnerID=8YFLogxK

U2 - 10.1007/s12272-011-0904-7

DO - 10.1007/s12272-011-0904-7

M3 - Article

C2 - 21975804

AN - SCOPUS:80755159039

SN - 0253-6269

VL - 34

SP - 1437

EP - 1442

JO - Archives of Pharmacal Research

JF - Archives of Pharmacal Research

IS - 9

ER -

A versatile synthetic approach to grandisol monoterpene pheromone

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this