A versatile synthetic approach to grandisol monoterpene pheromone

Young Taek Han; Nam Jung Kim; Jong Wha Jung; Hwayoung Yun; Sujin Lee; Young Ger Suh

doi:10.1007/s12272-011-0904-7

A versatile synthetic approach to grandisol monoterpene pheromone

Young Taek Han
, Nam Jung Kim
, Jong Wha Jung
, Hwayoung Yun
, Sujin Lee
, Young Ger Suh

Seoul National University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

Original language	English
Pages (from-to)	1437-1442
Number of pages	6
Journal	Archives of Pharmacal Research
Volume	34
Issue number	9
DOIs	https://doi.org/10.1007/s12272-011-0904-7
State	Published - Sep 2011

Keywords

Grandisol
Palladium
Pesticide
Pheromone
Synthesis

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10.1007/s12272-011-0904-7

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abstract = "A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.",

keywords = "Grandisol, Palladium, Pesticide, Pheromone, Synthesis",

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AU - Jung, Jong Wha

AU - Yun, Hwayoung

AU - Lee, Sujin

AU - Suh, Young Ger

PY - 2011/9

Y1 - 2011/9

N2 - A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

AB - A versatile and efficient synthetic procedure for the grandisol pheromone library has been established. The key feature of our synthesis involves a versatile and highly regioselective Pd(0)-catalyzed intramolecular allylic alkylation for the key cyclobutane skeleton of grandisol. In this connection, the concise synthesis of (±)-grandisol as well as mechanism study of Pd(0)-catalyzed regioselective cyclization as a key reaction have also been accomplished.

KW - Grandisol

KW - Palladium

KW - Pesticide

KW - Pheromone

KW - Synthesis

UR - https://www.scopus.com/pages/publications/80755159039

U2 - 10.1007/s12272-011-0904-7

DO - 10.1007/s12272-011-0904-7

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JO - Archives of Pharmacal Research

JF - Archives of Pharmacal Research

IS - 9

ER -

A versatile synthetic approach to grandisol monoterpene pheromone

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Keywords

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