Abstract
In the title compound, [Cu(ClO4)(C2H 3N)(C15H4N3O)]ClO4, the CuII ion is coordinated by three N atoms and a hydroxyl-O atom of the tetra-dentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetra-gonally distorted octa-hedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π-π inter-action [centroid-centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O -H⋯O hydrogen-bonding inter-action between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion.
Original language | English |
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Pages (from-to) | m143-m144 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 67 |
Issue number | 2 |
DOIs | |
State | Published - Feb 2011 |