Acetonitrile-{3-[bis(2-pyridylmethylκ-N)aminoκ-N] propanolκ-O}(perchloratoκ-O)copper(II) perchlorate

Jong Won Shin, Sankara Rao Rowthu, Hyun Jung Cho, Kil Sik Min

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Abstract

In the title compound, [Cu(ClO4)(C2H 3N)(C15H4N3O)]ClO4, the CuII ion is coordinated by three N atoms and a hydroxyl-O atom of the tetra-dentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetra-gonally distorted octa-hedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π-π inter-action [centroid-centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O -H⋯O hydrogen-bonding inter-action between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion.

Original languageEnglish
Pages (from-to)m143-m144
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number2
DOIs
StatePublished - Feb 2011

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