Adsorption of methane on porous metal carboxylates

Ji Sun Lee; Sung Hwa Jhung; Ji Woong Yoon; Young Kyu Hwang; Jong San Chang

doi:10.1016/j.jiec.2009.09.043

Adsorption of methane on porous metal carboxylates

Ji Sun Lee, Sung Hwa Jhung, Ji Woong Yoon, Young Kyu Hwang, Jong San Chang

Korea Research Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Porous metal carboxylates such as MIL-101 (Cr-terephthalate), MIL-100-Cr (Cr-trimesate) and MIL-100-Fe (Fe-trimesate) with very high porosity have been tested as potential adsorbents for methane storage materials. The MIL-101 shows one of the highest adsorption capacities for methane. The adsorption capacity per weight increases with increasing BET surface area or micropore volume irrespective of the structure, type of metal ions such as Cr³⁺ and Fe³⁺. This result suggests that the porous adsorbent for methane should have high porosity rather than special adsorption sites or structures.

Original language	English
Pages (from-to)	674-676
Number of pages	3
Journal	Journal of Industrial and Engineering Chemistry
Volume	15
Issue number	5
DOIs	https://doi.org/10.1016/j.jiec.2009.09.043
State	Published - 25 Sep 2009

Keywords

Adsorption
Metal carboxylate
Metal-organic framework
Methane

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10.1016/j.jiec.2009.09.043

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title = "Adsorption of methane on porous metal carboxylates",

abstract = "Porous metal carboxylates such as MIL-101 (Cr-terephthalate), MIL-100-Cr (Cr-trimesate) and MIL-100-Fe (Fe-trimesate) with very high porosity have been tested as potential adsorbents for methane storage materials. The MIL-101 shows one of the highest adsorption capacities for methane. The adsorption capacity per weight increases with increasing BET surface area or micropore volume irrespective of the structure, type of metal ions such as Cr3+ and Fe3+. This result suggests that the porous adsorbent for methane should have high porosity rather than special adsorption sites or structures.",

keywords = "Adsorption, Metal carboxylate, Metal-organic framework, Methane",

author = "Lee, {Ji Sun} and Jhung, {Sung Hwa} and Yoon, {Ji Woong} and Hwang, {Young Kyu} and Chang, {Jong San}",

year = "2009",

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T1 - Adsorption of methane on porous metal carboxylates

AU - Lee, Ji Sun

AU - Jhung, Sung Hwa

AU - Yoon, Ji Woong

AU - Hwang, Young Kyu

AU - Chang, Jong San

PY - 2009/9/25

Y1 - 2009/9/25

N2 - Porous metal carboxylates such as MIL-101 (Cr-terephthalate), MIL-100-Cr (Cr-trimesate) and MIL-100-Fe (Fe-trimesate) with very high porosity have been tested as potential adsorbents for methane storage materials. The MIL-101 shows one of the highest adsorption capacities for methane. The adsorption capacity per weight increases with increasing BET surface area or micropore volume irrespective of the structure, type of metal ions such as Cr3+ and Fe3+. This result suggests that the porous adsorbent for methane should have high porosity rather than special adsorption sites or structures.

AB - Porous metal carboxylates such as MIL-101 (Cr-terephthalate), MIL-100-Cr (Cr-trimesate) and MIL-100-Fe (Fe-trimesate) with very high porosity have been tested as potential adsorbents for methane storage materials. The MIL-101 shows one of the highest adsorption capacities for methane. The adsorption capacity per weight increases with increasing BET surface area or micropore volume irrespective of the structure, type of metal ions such as Cr3+ and Fe3+. This result suggests that the porous adsorbent for methane should have high porosity rather than special adsorption sites or structures.

KW - Adsorption

KW - Metal carboxylate

KW - Metal-organic framework

KW - Methane

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DO - 10.1016/j.jiec.2009.09.043

M3 - Article

AN - SCOPUS:70449712587

SN - 1226-086X

VL - 15

SP - 674

EP - 676

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

IS - 5

ER -

Adsorption of methane on porous metal carboxylates

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