Adsorption of TiCl4 on H/Si(1 0 0)-2 × 1 Surface

Manik Kumer Ghosh; Cheol Ho Choi

doi:10.1016/j.cplett.2008.07.025

Adsorption of TiCl₄ on H/Si(1 0 0)-2 × 1 Surface

Manik Kumer Ghosh, Cheol Ho Choi

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

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Abstract

The initial adsorption mechanism of TiCl₄ on H/Si(1 0 0)-2 × 1 surface was theoretically studied. The direct chlorination channel turned out to be kinetically the most favorable on H/Si(1 0 0)-2 × 1 surface, contrasting to the corresponding reactions on OH/Si(1 0 0)-2 × 1. Consequently, it would increase the surface Cl/Ti ratio.

Original language	English
Pages (from-to)	249-253
Number of pages	5
Journal	Chemical Physics Letters
Volume	461
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2008.07.025
State	Published - 20 Aug 2008

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title = "Adsorption of TiCl4 on H/Si(1 0 0)-2 × 1 Surface",

abstract = "The initial adsorption mechanism of TiCl4 on H/Si(1 0 0)-2 × 1 surface was theoretically studied. The direct chlorination channel turned out to be kinetically the most favorable on H/Si(1 0 0)-2 × 1 surface, contrasting to the corresponding reactions on OH/Si(1 0 0)-2 × 1. Consequently, it would increase the surface Cl/Ti ratio.",

author = "Ghosh, {Manik Kumer} and Choi, {Cheol Ho}",

year = "2008",

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doi = "10.1016/j.cplett.2008.07.025",

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AU - Ghosh, Manik Kumer

AU - Choi, Cheol Ho

PY - 2008/8/20

Y1 - 2008/8/20

N2 - The initial adsorption mechanism of TiCl4 on H/Si(1 0 0)-2 × 1 surface was theoretically studied. The direct chlorination channel turned out to be kinetically the most favorable on H/Si(1 0 0)-2 × 1 surface, contrasting to the corresponding reactions on OH/Si(1 0 0)-2 × 1. Consequently, it would increase the surface Cl/Ti ratio.

AB - The initial adsorption mechanism of TiCl4 on H/Si(1 0 0)-2 × 1 surface was theoretically studied. The direct chlorination channel turned out to be kinetically the most favorable on H/Si(1 0 0)-2 × 1 surface, contrasting to the corresponding reactions on OH/Si(1 0 0)-2 × 1. Consequently, it would increase the surface Cl/Ti ratio.

UR - http://www.scopus.com/inward/record.url?scp=48749122795&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2008.07.025

DO - 10.1016/j.cplett.2008.07.025

M3 - Article

AN - SCOPUS:48749122795

SN - 0009-2614

VL - 461

SP - 249

EP - 253

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Adsorption of TiCl₄ on H/Si(1 0 0)-2 × 1 Surface

Abstract

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