Ammonia cluster anions and their relationship to ammoniated (solvated) electrons: The photoelectron spectra of (NH3)n=41-1100-

H. W. Sarkas; S. T. Arnold; J. G. Eaton; G. H. Lee; K. H. Bowen

doi:10.1063/1.1451057

Ammonia cluster anions and their relationship to ammoniated (solvated) electrons: The photoelectron spectra of (NH₃)_n=41-1100^-

H. W. Sarkas, S. T. Arnold, J. G. Eaton, G. H. Lee, K. H. Bowen

Johns Hopkins University

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Abstract

The negative ion photoelectron spectra of (NH₃)^-_{n = 41 - 1100}, using 2.540 eV photons was discussed. It was found that vertical detachment energies (VDE) of the cluster anions increased smoothly from 0.55 eV for n = 41 to 1.05 eV for n = 1100. The analysis of VDE data implied that the embryonic ammoniated electrons were generated in solid ammonia environments, consistent with the source condition under which they were produced.

Original language	English
Pages (from-to)	5731-5737
Number of pages	7
Journal	Journal of Chemical Physics
Volume	116
Issue number	13
DOIs	https://doi.org/10.1063/1.1451057
State	Published - 1 Apr 2002

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abstract = "The negative ion photoelectron spectra of (NH3)-n = 41 - 1100, using 2.540 eV photons was discussed. It was found that vertical detachment energies (VDE) of the cluster anions increased smoothly from 0.55 eV for n = 41 to 1.05 eV for n = 1100. The analysis of VDE data implied that the embryonic ammoniated electrons were generated in solid ammonia environments, consistent with the source condition under which they were produced.",

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AU - Eaton, J. G.

AU - Lee, G. H.

AU - Bowen, K. H.

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N2 - The negative ion photoelectron spectra of (NH3)-n = 41 - 1100, using 2.540 eV photons was discussed. It was found that vertical detachment energies (VDE) of the cluster anions increased smoothly from 0.55 eV for n = 41 to 1.05 eV for n = 1100. The analysis of VDE data implied that the embryonic ammoniated electrons were generated in solid ammonia environments, consistent with the source condition under which they were produced.

AB - The negative ion photoelectron spectra of (NH3)-n = 41 - 1100, using 2.540 eV photons was discussed. It was found that vertical detachment energies (VDE) of the cluster anions increased smoothly from 0.55 eV for n = 41 to 1.05 eV for n = 1100. The analysis of VDE data implied that the embryonic ammoniated electrons were generated in solid ammonia environments, consistent with the source condition under which they were produced.

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Ammonia cluster anions and their relationship to ammoniated (solvated) electrons: The photoelectron spectra of (NH₃)_n=41-1100^-

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