An efficient dealkylative addition of trialkylamines to dialkyl acetylenedicarboxylates in the presence of a metallic chloride

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Abstract

Dialkyl acetylenedicarboxylates react effectively with an array of trialkylamines in dioxane at 80°C in the presence of a metallic chloride to afford the corresponding aminomaleates in good yields.

Original languageEnglish
Pages (from-to)1415-1417
Number of pages3
JournalTetrahedron Letters
Volume46
Issue number9
DOIs
StatePublished - 28 Feb 2005

Keywords

  • Aminomaleates
  • Dialkyl acetylenedicarboxylates
  • Metallic chlorides
  • Trialkylamines

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