An in-situ simultaneous SAXS and WAXS survey of PEBAX® nanocomposites reinforced with organoclay and POSS during uniaxial deformation

Tahseen Kamal; Soo Young Park; Myong Chan Choi; Young Wook Chang; Wei Tsung Chuang; U. Ser Jeng

doi:10.1016/j.polymer.2012.05.037

An in-situ simultaneous SAXS and WAXS survey of PEBAX^® nanocomposites reinforced with organoclay and POSS during uniaxial deformation

Tahseen Kamal, Soo Young Park, Myong Chan Choi, Young Wook Chang, Wei Tsung Chuang, U. Ser Jeng

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Poly(ether-block-amide) (PEBA), commercially known as PEBAX ^®, nanocomposites filled with organically modified clay (Cloisite 30B) and trisilinolphenyl-polyhedral oligomeric silsesquioxane (tsp-POSS) were prepared by a melt mixing method, respectively. The structures of the nanocomposites were investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and in-situ simultaneous small and wide angle X-ray scatterings (SAXS and WAXS) during uniaxial deformation. The FT-IR spectra showed the hydrogen bonding between the fillers and the PEBA which helped to disperse the fillers in the polymer matrix. The crystallinities and mechanical properties of the nanocomposites were improved compared to the neat polymer. Their origins were studied with an in-situ simultaneous SAXS and WAXS technique during the uniaxial deformation.

Original language	English
Pages (from-to)	3360-3367
Number of pages	8
Journal	Polymer
Volume	53
Issue number	15
DOIs	https://doi.org/10.1016/j.polymer.2012.05.037
State	Published - 6 Jul 2012

Keywords

Organoclay
Poly(ether-b-amide)
Trisilinolphenyl-POSS

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10.1016/j.polymer.2012.05.037

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@article{c1a6c0bc0147462f944d08a29bd24808,

title = "An in-situ simultaneous SAXS and WAXS survey of PEBAX{\textregistered} nanocomposites reinforced with organoclay and POSS during uniaxial deformation",

abstract = "Poly(ether-block-amide) (PEBA), commercially known as PEBAX {\textregistered}, nanocomposites filled with organically modified clay (Cloisite 30B) and trisilinolphenyl-polyhedral oligomeric silsesquioxane (tsp-POSS) were prepared by a melt mixing method, respectively. The structures of the nanocomposites were investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and in-situ simultaneous small and wide angle X-ray scatterings (SAXS and WAXS) during uniaxial deformation. The FT-IR spectra showed the hydrogen bonding between the fillers and the PEBA which helped to disperse the fillers in the polymer matrix. The crystallinities and mechanical properties of the nanocomposites were improved compared to the neat polymer. Their origins were studied with an in-situ simultaneous SAXS and WAXS technique during the uniaxial deformation.",

keywords = "Organoclay, Poly(ether-b-amide), Trisilinolphenyl-POSS",

author = "Tahseen Kamal and Park, {Soo Young} and Choi, {Myong Chan} and Chang, {Young Wook} and Chuang, {Wei Tsung} and Jeng, {U. Ser}",

year = "2012",

month = jul,

day = "6",

doi = "10.1016/j.polymer.2012.05.037",

language = "English",

volume = "53",

pages = "3360--3367",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "15",

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TY - JOUR

T1 - An in-situ simultaneous SAXS and WAXS survey of PEBAX® nanocomposites reinforced with organoclay and POSS during uniaxial deformation

AU - Kamal, Tahseen

AU - Park, Soo Young

AU - Choi, Myong Chan

AU - Chang, Young Wook

AU - Chuang, Wei Tsung

AU - Jeng, U. Ser

PY - 2012/7/6

Y1 - 2012/7/6

N2 - Poly(ether-block-amide) (PEBA), commercially known as PEBAX ®, nanocomposites filled with organically modified clay (Cloisite 30B) and trisilinolphenyl-polyhedral oligomeric silsesquioxane (tsp-POSS) were prepared by a melt mixing method, respectively. The structures of the nanocomposites were investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and in-situ simultaneous small and wide angle X-ray scatterings (SAXS and WAXS) during uniaxial deformation. The FT-IR spectra showed the hydrogen bonding between the fillers and the PEBA which helped to disperse the fillers in the polymer matrix. The crystallinities and mechanical properties of the nanocomposites were improved compared to the neat polymer. Their origins were studied with an in-situ simultaneous SAXS and WAXS technique during the uniaxial deformation.

AB - Poly(ether-block-amide) (PEBA), commercially known as PEBAX ®, nanocomposites filled with organically modified clay (Cloisite 30B) and trisilinolphenyl-polyhedral oligomeric silsesquioxane (tsp-POSS) were prepared by a melt mixing method, respectively. The structures of the nanocomposites were investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and in-situ simultaneous small and wide angle X-ray scatterings (SAXS and WAXS) during uniaxial deformation. The FT-IR spectra showed the hydrogen bonding between the fillers and the PEBA which helped to disperse the fillers in the polymer matrix. The crystallinities and mechanical properties of the nanocomposites were improved compared to the neat polymer. Their origins were studied with an in-situ simultaneous SAXS and WAXS technique during the uniaxial deformation.

KW - Organoclay

KW - Poly(ether-b-amide)

KW - Trisilinolphenyl-POSS

UR - http://www.scopus.com/inward/record.url?scp=84862770961&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2012.05.037

DO - 10.1016/j.polymer.2012.05.037

M3 - Article

AN - SCOPUS:84862770961

SN - 0032-3861

VL - 53

SP - 3360

EP - 3367

JO - Polymer

JF - Polymer

IS - 15

ER -

An in-situ simultaneous SAXS and WAXS survey of PEBAX^® nanocomposites reinforced with organoclay and POSS during uniaxial deformation

Abstract

Keywords

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