Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties

Ihsan Ullah; Jong Won Shin; Ryuya Tokunaga; Shinya Hayami; Hye Jin Shin; Kil Sik Min

doi:10.3390/cryst12081096

Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties

Ihsan Ullah, Jong Won Shin, Ryuya Tokunaga, Shinya Hayami, Hye Jin Shin, Kil Sik Min

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A one-dimensional (1D) coordination polymer [Cu₂(bpba)(CH₃COO)₄] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)₂(H₂O)(NO₃)](NO₃)∙2H₂O∙MeOH (2) were synthesized by the reaction between Cu(CH₃COO)₂∙H₂O/Cu(NO₃)₂∙3H₂O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, whereas polymer 2 exhibits strong emissions only at 464 nm. The emissions are strongly dependent on the geometry of the Cu(II) ions linked by the bpba and anionic ligands. Polymer 1 exhibits a very strong antiferromagnetic interaction within the paddle-wheel dimer, whereas polymer 2 exhibits a very weak antiferromagnetic interaction through the bpba linkers and/or space.

Original language	English
Article number	1096
Journal	Crystals
Volume	12
Issue number	8
DOIs	https://doi.org/10.3390/cryst12081096
State	Published - Aug 2022

Keywords

Cu(II) ion
coordination polymer
crystal engineering
magnetism
photoluminescence
structure

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@article{2751a8aaca864cd2b09b0b44ec0b048a,

title = "Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties",

abstract = "A one-dimensional (1D) coordination polymer [Cu2(bpba)(CH3COO)4] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)2(H2O)(NO3)](NO3)∙2H2O∙MeOH (2) were synthesized by the reaction between Cu(CH3COO)2∙H2O/Cu(NO3)2∙3H2O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, whereas polymer 2 exhibits strong emissions only at 464 nm. The emissions are strongly dependent on the geometry of the Cu(II) ions linked by the bpba and anionic ligands. Polymer 1 exhibits a very strong antiferromagnetic interaction within the paddle-wheel dimer, whereas polymer 2 exhibits a very weak antiferromagnetic interaction through the bpba linkers and/or space.",

keywords = "Cu(II) ion, coordination polymer, crystal engineering, magnetism, photoluminescence, structure",

author = "Ihsan Ullah and Shin, \{Jong Won\} and Ryuya Tokunaga and Shinya Hayami and Shin, \{Hye Jin\} and Min, \{Kil Sik\}",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = aug,

doi = "10.3390/cryst12081096",

language = "English",

volume = "12",

journal = "Crystals",

issn = "2073-4352",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "8",

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TY - JOUR

T1 - Anion-Dependent Cu(II) Coordination Polymers

T2 - Geometric, Magnetic and Luminescent Properties

AU - Ullah, Ihsan

AU - Shin, Jong Won

AU - Tokunaga, Ryuya

AU - Hayami, Shinya

AU - Shin, Hye Jin

AU - Min, Kil Sik

PY - 2022/8

Y1 - 2022/8

N2 - A one-dimensional (1D) coordination polymer [Cu2(bpba)(CH3COO)4] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)2(H2O)(NO3)](NO3)∙2H2O∙MeOH (2) were synthesized by the reaction between Cu(CH3COO)2∙H2O/Cu(NO3)2∙3H2O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, whereas polymer 2 exhibits strong emissions only at 464 nm. The emissions are strongly dependent on the geometry of the Cu(II) ions linked by the bpba and anionic ligands. Polymer 1 exhibits a very strong antiferromagnetic interaction within the paddle-wheel dimer, whereas polymer 2 exhibits a very weak antiferromagnetic interaction through the bpba linkers and/or space.

AB - A one-dimensional (1D) coordination polymer [Cu2(bpba)(CH3COO)4] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)2(H2O)(NO3)](NO3)∙2H2O∙MeOH (2) were synthesized by the reaction between Cu(CH3COO)2∙H2O/Cu(NO3)2∙3H2O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, whereas polymer 2 exhibits strong emissions only at 464 nm. The emissions are strongly dependent on the geometry of the Cu(II) ions linked by the bpba and anionic ligands. Polymer 1 exhibits a very strong antiferromagnetic interaction within the paddle-wheel dimer, whereas polymer 2 exhibits a very weak antiferromagnetic interaction through the bpba linkers and/or space.

KW - Cu(II) ion

KW - coordination polymer

KW - crystal engineering

KW - magnetism

KW - photoluminescence

KW - structure

UR - http://www.scopus.com/inward/record.url?scp=85137399383&partnerID=8YFLogxK

U2 - 10.3390/cryst12081096

DO - 10.3390/cryst12081096

M3 - Article

AN - SCOPUS:85137399383

SN - 2073-4352

VL - 12

JO - Crystals

JF - Crystals

IS - 8

M1 - 1096

ER -

Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties

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