Anomalous magnetic properties of MnO nanoclusters

Gang H. Lee, Seung H. Huh, Jin W. Jeong, Byeong J. Choi, Seung H. Kim, Hyeong C. Ri

Research output: Contribution to journalArticlepeer-review

186 Scopus citations

Abstract

In this communication, we experimentally report, for the first time, that the MnO nanoclusters with cluster diameters of 5-10 nm show a ferromagnetic behavior with a phase transition from ferromagnetic to paramagnetic phases at 27 K even though their bulk phase is antiferromagnetic. We observed large coercivities up to 9500 Oe and a large remanence of 1.72 emu/g at 2 K, which are typically observed values for ferromagnetic materials. Although it is not clear, this abnormal ferromagnetic behavior of MnO nanoclusters may arise from cluster size effects.

Original languageEnglish
Pages (from-to)12094-12095
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number41
DOIs
StatePublished - 16 Oct 2002

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