Abstract
In this communication, we experimentally report, for the first time, that the MnO nanoclusters with cluster diameters of 5-10 nm show a ferromagnetic behavior with a phase transition from ferromagnetic to paramagnetic phases at 27 K even though their bulk phase is antiferromagnetic. We observed large coercivities up to 9500 Oe and a large remanence of 1.72 emu/g at 2 K, which are typically observed values for ferromagnetic materials. Although it is not clear, this abnormal ferromagnetic behavior of MnO nanoclusters may arise from cluster size effects.
Original language | English |
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Pages (from-to) | 12094-12095 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 124 |
Issue number | 41 |
DOIs | |
State | Published - 16 Oct 2002 |