Bis-rhodium hexaphyrins: Metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Harapriya Rath; Naoki Aratani; Jong Min Lim; Jae Seok Lee; Dongho Kim; Hiroshi Shinokubo; Atsuhiro Osuka

doi:10.1039/b905859a

Bis-rhodium hexaphyrins: Metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Harapriya Rath, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)₂] ₂ resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

Original language	English
Pages (from-to)	3762-3764
Number of pages	3
Journal	Chemical Communications
Issue number	25
DOIs	https://doi.org/10.1039/b905859a
State	Published - 2009

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title = "Bis-rhodium hexaphyrins: Metalation of [28]hexaphyrin and a smooth H{\"u}ckel aromatic-antiaromatic interconversion",

abstract = "Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)2] 2 resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.",

author = "Harapriya Rath and Naoki Aratani and Lim, {Jong Min} and Lee, {Jae Seok} and Dongho Kim and Hiroshi Shinokubo and Atsuhiro Osuka",

year = "2009",

doi = "10.1039/b905859a",

language = "English",

pages = "3762--3764",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "25",

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TY - JOUR

T1 - Bis-rhodium hexaphyrins

T2 - Metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

AU - Rath, Harapriya

AU - Aratani, Naoki

AU - Lim, Jong Min

AU - Lee, Jae Seok

AU - Kim, Dongho

AU - Shinokubo, Hiroshi

AU - Osuka, Atsuhiro

PY - 2009

Y1 - 2009

N2 - Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)2] 2 resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

AB - Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)2] 2 resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.

UR - http://www.scopus.com/inward/record.url?scp=67649881396&partnerID=8YFLogxK

U2 - 10.1039/b905859a

DO - 10.1039/b905859a

M3 - Article

AN - SCOPUS:67649881396

SN - 1359-7345

SP - 3762

EP - 3764

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Bis-rhodium hexaphyrins: Metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion

Abstract

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