Bis(di-2-pyridylmethanediol-κ3 N,O,N′)nickel(II) dibenzoate

Jin Hoon Kim; Du Hyun Kim; Pan Gi Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S160053681003669X

Bis(di-2-pyridylmethanediol-κ³ N,O,N′)nickel(II) dibenzoate

Jin Hoon Kim
, Du Hyun Kim
, Pan Gi Kim
, Cheal Kim
, Youngmee Kim

Department of Forest Ecology and Protection

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The title compound, [Ni(C₁₁H₁₀N₂O ₂)₂](C₇H₅O₂) ₂, consists of an Ni^II ion coordinated by two tridentate chelating (2-py)₂C(OH)₂ ligands (py is pyridyl) and two benzoate anions. The Ni^II ion is located on a twofold rotation axis, and its geometry is distorted octa-hedral. The gem-diol ligand (2-py) ₂C(OH)₂ adopts an η¹:η¹: η¹ coordination mode. There are O - H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions.

Original language	English
Pages (from-to)	m1281-m1282
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	10
DOIs	https://doi.org/10.1107/S160053681003669X
State	Published - Oct 2010

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@article{a16a1b97ebd74a4594452532794e518f,

title = "Bis(di-2-pyridylmethanediol-κ3 N,O,N′)nickel(II) dibenzoate",

abstract = "The title compound, [Ni(C11H10N2O 2)2](C7H5O2) 2, consists of an NiII ion coordinated by two tridentate chelating (2-py)2C(OH)2 ligands (py is pyridyl) and two benzoate anions. The NiII ion is located on a twofold rotation axis, and its geometry is distorted octa-hedral. The gem-diol ligand (2-py) 2C(OH)2 adopts an η1:η1: η1 coordination mode. There are O - H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions.",

author = "Kim, \{Jin Hoon\} and Kim, \{Du Hyun\} and Kim, \{Pan Gi\} and Cheal Kim and Youngmee Kim",

year = "2010",

month = oct,

doi = "10.1107/S160053681003669X",

language = "English",

volume = "66",

pages = "m1281--m1282",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - Bis(di-2-pyridylmethanediol-κ3 N,O,N′)nickel(II) dibenzoate

AU - Kim, Jin Hoon

AU - Kim, Du Hyun

AU - Kim, Pan Gi

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2010/10

Y1 - 2010/10

N2 - The title compound, [Ni(C11H10N2O 2)2](C7H5O2) 2, consists of an NiII ion coordinated by two tridentate chelating (2-py)2C(OH)2 ligands (py is pyridyl) and two benzoate anions. The NiII ion is located on a twofold rotation axis, and its geometry is distorted octa-hedral. The gem-diol ligand (2-py) 2C(OH)2 adopts an η1:η1: η1 coordination mode. There are O - H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions.

AB - The title compound, [Ni(C11H10N2O 2)2](C7H5O2) 2, consists of an NiII ion coordinated by two tridentate chelating (2-py)2C(OH)2 ligands (py is pyridyl) and two benzoate anions. The NiII ion is located on a twofold rotation axis, and its geometry is distorted octa-hedral. The gem-diol ligand (2-py) 2C(OH)2 adopts an η1:η1: η1 coordination mode. There are O - H⋯O hydrogen bonds between the gem-diol ligands and benzoate anions.

UR - https://www.scopus.com/pages/publications/77957835876

U2 - 10.1107/S160053681003669X

DO - 10.1107/S160053681003669X

M3 - Article

AN - SCOPUS:77957835876

SN - 1600-5368

VL - 66

SP - m1281-m1282

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Bis(di-2-pyridylmethanediol-κ³ N,O,N′)nickel(II) dibenzoate

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