Bright white light emission from (Gd3+ /Dy3+) dual doped transparent lithium aluminum borate glasses for W- LED application

W. Rittisut; N. Wantana; Y. Ruangtaweep; P. Mool-am-kha; J. Padchasri; S. Rujirawat; P. Manyum; R. Yimnirun; P. Kidkhunthod; A. Prasatkhetragarn; S. Kothan; H. J. Kim; J. Kaewkhao

doi:10.1016/j.optmat.2021.111705

Bright white light emission from (Gd³⁺ /Dy³⁺) dual doped transparent lithium aluminum borate glasses for W- LED application

W. Rittisut, N. Wantana, Y. Ruangtaweep, P. Mool-am-kha, J. Padchasri, S. Rujirawat, P. Manyum, R. Yimnirun, P. Kidkhunthod, A. Prasatkhetragarn, S. Kothan, H. J. Kim, J. Kaewkhao

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17 Scopus citations

Abstract

The improving optical and luminescence properties of Dy³⁺ and Gd³⁺ dual doped lithium aluminum borate glasses with composition 25Li₂O-5.0Al₂O₃-2.5Gd₂O₃-(67.5-X)B₂O₃-XDy₂O₃ glasses were successfully developed. The as-synthesis composite used conventional melt-quenching processes. All glass samples doped with Dy₂O₃ show an enhanced emission intensity (photo and radioluminescence spectra) with increasing the concentration of Dy₂O₃ up to 1.0 mol%, and beyond that, concentration quenching has occurred for all samples. The experimental decay times calculated from the decay profiles have been gradually declined with an increase in Dy³⁺ ion concentration. The chromaticity coordinates (CIE 1931) were located in the white light region of the color chromaticity diagram. The Dy-doping glasses synthesized show the prevalent presence of Dy³⁺also, the presence of the trivalent oxidation state in the glasses series. Therefore, the results confirm that the Dy³⁺-doped glasses could be useable for white-LEDs applications.

Original language	English
Article number	111705
Journal	Optical Materials
Volume	122
DOIs	https://doi.org/10.1016/j.optmat.2021.111705
State	Published - Dec 2021

Keywords

Borate glass
Luminescence
White-LEDs

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10.1016/j.optmat.2021.111705

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Rittisut, W., Wantana, N., Ruangtaweep, Y., Mool-am-kha, P., Padchasri, J., Rujirawat, S., Manyum, P., Yimnirun, R., Kidkhunthod, P., Prasatkhetragarn, A., Kothan, S., Kim, H. J., & Kaewkhao, J. (2021). Bright white light emission from (Gd³⁺ /Dy³⁺) dual doped transparent lithium aluminum borate glasses for W- LED application. Optical Materials, 122, Article 111705. https://doi.org/10.1016/j.optmat.2021.111705

@article{dcdda4d49b82463db9f2f087e3913dd3,

title = "Bright white light emission from (Gd3+ /Dy3+) dual doped transparent lithium aluminum borate glasses for W- LED application",

abstract = "The improving optical and luminescence properties of Dy3+ and Gd3+ dual doped lithium aluminum borate glasses with composition 25Li2O-5.0Al2O3-2.5Gd2O3-(67.5-X)B2O3-XDy2O3 glasses were successfully developed. The as-synthesis composite used conventional melt-quenching processes. All glass samples doped with Dy2O3 show an enhanced emission intensity (photo and radioluminescence spectra) with increasing the concentration of Dy2O3 up to 1.0 mol%, and beyond that, concentration quenching has occurred for all samples. The experimental decay times calculated from the decay profiles have been gradually declined with an increase in Dy3+ ion concentration. The chromaticity coordinates (CIE 1931) were located in the white light region of the color chromaticity diagram. The Dy-doping glasses synthesized show the prevalent presence of Dy3+also, the presence of the trivalent oxidation state in the glasses series. Therefore, the results confirm that the Dy3+-doped glasses could be useable for white-LEDs applications.",

keywords = "Borate glass, Luminescence, White-LEDs",

author = "W. Rittisut and N. Wantana and Y. Ruangtaweep and P. Mool-am-kha and J. Padchasri and S. Rujirawat and P. Manyum and R. Yimnirun and P. Kidkhunthod and A. Prasatkhetragarn and S. Kothan and Kim, {H. J.} and J. Kaewkhao",

note = "Publisher Copyright: {\textcopyright} 2021",

year = "2021",

month = dec,

doi = "10.1016/j.optmat.2021.111705",

language = "English",

volume = "122",

journal = "Optical Materials",

issn = "0925-3467",

publisher = "Elsevier B.V.",

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Rittisut, W, Wantana, N, Ruangtaweep, Y, Mool-am-kha, P, Padchasri, J, Rujirawat, S, Manyum, P, Yimnirun, R, Kidkhunthod, P, Prasatkhetragarn, A, Kothan, S, Kim, HJ & Kaewkhao, J 2021, 'Bright white light emission from (Gd³⁺ /Dy³⁺) dual doped transparent lithium aluminum borate glasses for W- LED application', Optical Materials, vol. 122, 111705. https://doi.org/10.1016/j.optmat.2021.111705

TY - JOUR

T1 - Bright white light emission from (Gd3+ /Dy3+) dual doped transparent lithium aluminum borate glasses for W- LED application

AU - Rittisut, W.

AU - Wantana, N.

AU - Ruangtaweep, Y.

AU - Mool-am-kha, P.

AU - Padchasri, J.

AU - Rujirawat, S.

AU - Manyum, P.

AU - Yimnirun, R.

AU - Kidkhunthod, P.

AU - Prasatkhetragarn, A.

AU - Kothan, S.

AU - Kim, H. J.

AU - Kaewkhao, J.

PY - 2021/12

Y1 - 2021/12

N2 - The improving optical and luminescence properties of Dy3+ and Gd3+ dual doped lithium aluminum borate glasses with composition 25Li2O-5.0Al2O3-2.5Gd2O3-(67.5-X)B2O3-XDy2O3 glasses were successfully developed. The as-synthesis composite used conventional melt-quenching processes. All glass samples doped with Dy2O3 show an enhanced emission intensity (photo and radioluminescence spectra) with increasing the concentration of Dy2O3 up to 1.0 mol%, and beyond that, concentration quenching has occurred for all samples. The experimental decay times calculated from the decay profiles have been gradually declined with an increase in Dy3+ ion concentration. The chromaticity coordinates (CIE 1931) were located in the white light region of the color chromaticity diagram. The Dy-doping glasses synthesized show the prevalent presence of Dy3+also, the presence of the trivalent oxidation state in the glasses series. Therefore, the results confirm that the Dy3+-doped glasses could be useable for white-LEDs applications.

AB - The improving optical and luminescence properties of Dy3+ and Gd3+ dual doped lithium aluminum borate glasses with composition 25Li2O-5.0Al2O3-2.5Gd2O3-(67.5-X)B2O3-XDy2O3 glasses were successfully developed. The as-synthesis composite used conventional melt-quenching processes. All glass samples doped with Dy2O3 show an enhanced emission intensity (photo and radioluminescence spectra) with increasing the concentration of Dy2O3 up to 1.0 mol%, and beyond that, concentration quenching has occurred for all samples. The experimental decay times calculated from the decay profiles have been gradually declined with an increase in Dy3+ ion concentration. The chromaticity coordinates (CIE 1931) were located in the white light region of the color chromaticity diagram. The Dy-doping glasses synthesized show the prevalent presence of Dy3+also, the presence of the trivalent oxidation state in the glasses series. Therefore, the results confirm that the Dy3+-doped glasses could be useable for white-LEDs applications.

KW - Borate glass

KW - Luminescence

KW - White-LEDs

UR - http://www.scopus.com/inward/record.url?scp=85117386317&partnerID=8YFLogxK

U2 - 10.1016/j.optmat.2021.111705

DO - 10.1016/j.optmat.2021.111705

M3 - Article

AN - SCOPUS:85117386317

SN - 0925-3467

VL - 122

JO - Optical Materials

JF - Optical Materials

M1 - 111705

ER -

Bright white light emission from (Gd³⁺ /Dy³⁺) dual doped transparent lithium aluminum borate glasses for W- LED application

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Keywords

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