Bundle formation in parallel aligned polymers with competing interactions

Sandipan Dutta, P. Benetatos, Y. S. Jho

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Aggregation of like-charged polymers is widely observed in biological- and soft-matter systems. In many systems, bundles are formed when a short-range attraction of diverse physical origin like charge bridging, hydrogen bonding or hydrophobic interaction, overcomes the longer-range charge repulsion. In this letter, we present a general mechanism of bundle formation in these systems as the breaking of the translational invariance in parallel aligned polymers with competing interactions of this type. We derive a criterion for finite-sized bundle formation as well as for macroscopic phase separation (formation of infinite bundles).

Original languageEnglish
Article number28001
JournalEurophysics Letters
Volume114
Issue number2
DOIs
StatePublished - Apr 2016

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