Carbon-carbon bond formation between secondary alcohols and aldehydes under ruthenium-catalyzed redox shuttle

Chan Sik Cho; Bok Tae Kim; Nam Sik Yoon

doi:10.1002/aoc.1829

Carbon-carbon bond formation between secondary alcohols and aldehydes under ruthenium-catalyzed redox shuttle

Chan Sik Cho, Bok Tae Kim, Nam Sik Yoon

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Secondary alcohols are coupled with aldehydes in dioxane in the presence of a catalytic amount of a ruthenium catalyst along with KOH to give coupled ketones or coupled secondary alcohols depending on the molar ratio of secondary alcohols to aldehydes and the presence (or absence) of a sacrificial hydrogen acceptor.

Original language	English
Pages (from-to)	695-698
Number of pages	4
Journal	Applied Organometallic Chemistry
Volume	25
Issue number	9
DOIs	https://doi.org/10.1002/aoc.1829
State	Published - Sep 2011

Keywords

aldehydes
carbon-carbon bond formation
redox
ruthenium catalyst
secondary alcohols

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10.1002/aoc.1829

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title = "Carbon-carbon bond formation between secondary alcohols and aldehydes under ruthenium-catalyzed redox shuttle",

abstract = "Secondary alcohols are coupled with aldehydes in dioxane in the presence of a catalytic amount of a ruthenium catalyst along with KOH to give coupled ketones or coupled secondary alcohols depending on the molar ratio of secondary alcohols to aldehydes and the presence (or absence) of a sacrificial hydrogen acceptor.",

keywords = "aldehydes, carbon-carbon bond formation, redox, ruthenium catalyst, secondary alcohols",

author = "Cho, {Chan Sik} and Kim, {Bok Tae} and Yoon, {Nam Sik}",

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language = "English",

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AU - Cho, Chan Sik

AU - Kim, Bok Tae

AU - Yoon, Nam Sik

PY - 2011/9

Y1 - 2011/9

N2 - Secondary alcohols are coupled with aldehydes in dioxane in the presence of a catalytic amount of a ruthenium catalyst along with KOH to give coupled ketones or coupled secondary alcohols depending on the molar ratio of secondary alcohols to aldehydes and the presence (or absence) of a sacrificial hydrogen acceptor.

AB - Secondary alcohols are coupled with aldehydes in dioxane in the presence of a catalytic amount of a ruthenium catalyst along with KOH to give coupled ketones or coupled secondary alcohols depending on the molar ratio of secondary alcohols to aldehydes and the presence (or absence) of a sacrificial hydrogen acceptor.

KW - aldehydes

KW - carbon-carbon bond formation

KW - redox

KW - ruthenium catalyst

KW - secondary alcohols

UR - http://www.scopus.com/inward/record.url?scp=81155159650&partnerID=8YFLogxK

U2 - 10.1002/aoc.1829

DO - 10.1002/aoc.1829

M3 - Article

AN - SCOPUS:81155159650

SN - 0268-2605

VL - 25

SP - 695

EP - 698

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 9

ER -

Carbon-carbon bond formation between secondary alcohols and aldehydes under ruthenium-catalyzed redox shuttle

Abstract

Keywords

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