Catena-Poly[[bis-(2-hydroxy-2-phenylacetato-2O 1,O2)zinc(II)] - 1,2-di-4-pyridylethane-2 N:N′]

Seung Man Yu; Dong Hoon Shin; Pan Gi Kim; Cheal Kim; Youngmee Kim

doi:10.1107/S1600536809030281

Catena-Poly[[bis-(2-hydroxy-2-phenylacetato-²O ¹,O²)zinc(II)] - 1,2-di-4-pyridylethane-² N:N′]

Seung Man Yu
, Dong Hoon Shin
, Pan Gi Kim
, Cheal Kim
, Youngmee Kim

Department of Forest Ecology and Protection

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The title compound, [Zn(C₈H₆O₃) ₂(C₁₂H₁₂N₂)] n, consists of [Zn(Hopa)₂] (H₂opa = 2-hydr-oxy-2-phenyl-acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C - C bond. The geometry around the Zn^II ion is distorted octa-hedral, constructed by four O atoms from two Hopa^- ligands and two N atoms from two bridging bpe ligands. O - H⋯O hydrogen bonds link the chains, forming a three-dimensional network.

Original language	English
Pages (from-to)	m1045-m1046
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	9
DOIs	https://doi.org/10.1107/S1600536809030281
State	Published - 2009

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@article{997ba46357664709a86a982905ef2432,

title = "Catena-Poly[[bis-(2-hydroxy-2-phenylacetato-2O 1,O2)zinc(II)] - 1,2-di-4-pyridylethane-2 N:N′]",

abstract = "The title compound, [Zn(C8H6O3) 2(C12H12N2)] n, consists of [Zn(Hopa)2] (H2opa = 2-hydr-oxy-2-phenyl-acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C - C bond. The geometry around the ZnII ion is distorted octa-hedral, constructed by four O atoms from two Hopa- ligands and two N atoms from two bridging bpe ligands. O - H⋯O hydrogen bonds link the chains, forming a three-dimensional network.",

author = "Yu, \{Seung Man\} and Shin, \{Dong Hoon\} and Kim, \{Pan Gi\} and Cheal Kim and Youngmee Kim",

year = "2009",

doi = "10.1107/S1600536809030281",

language = "English",

volume = "65",

pages = "m1045--m1046",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

TY - JOUR

T1 - Catena-Poly[[bis-(2-hydroxy-2-phenylacetato-2O 1,O2)zinc(II)] - 1,2-di-4-pyridylethane-2 N:N′]

AU - Yu, Seung Man

AU - Shin, Dong Hoon

AU - Kim, Pan Gi

AU - Kim, Cheal

AU - Kim, Youngmee

PY - 2009

Y1 - 2009

N2 - The title compound, [Zn(C8H6O3) 2(C12H12N2)] n, consists of [Zn(Hopa)2] (H2opa = 2-hydr-oxy-2-phenyl-acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C - C bond. The geometry around the ZnII ion is distorted octa-hedral, constructed by four O atoms from two Hopa- ligands and two N atoms from two bridging bpe ligands. O - H⋯O hydrogen bonds link the chains, forming a three-dimensional network.

AB - The title compound, [Zn(C8H6O3) 2(C12H12N2)] n, consists of [Zn(Hopa)2] (H2opa = 2-hydr-oxy-2-phenyl-acetic acid or mandelic acid) units bridged by 1,2-di-4-pyridylethane (bpe) ligands, forming a polymeric chain developing parallel to the b axis. The bridging bpe ligand is arranged around a twofold axis passing through the middle of the ethane C - C bond. The geometry around the ZnII ion is distorted octa-hedral, constructed by four O atoms from two Hopa- ligands and two N atoms from two bridging bpe ligands. O - H⋯O hydrogen bonds link the chains, forming a three-dimensional network.

UR - https://www.scopus.com/pages/publications/70249103122

U2 - 10.1107/S1600536809030281

DO - 10.1107/S1600536809030281

M3 - Article

AN - SCOPUS:70249103122

SN - 1600-5368

VL - 65

SP - m1045-m1046

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Catena-Poly[[bis-(2-hydroxy-2-phenylacetato-²O ¹,O²)zinc(II)] - 1,2-di-4-pyridylethane-² N:N′]

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