Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C60

Won Young Cha; Ahreum Ahn; Taeyeon Kim; Juwon Oh; Rashid Ali; Jung Su Park; Dongho Kim

doi:10.1039/c9cc03928g

Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C₆₀

Won Young Cha, Ahreum Ahn, Taeyeon Kim, Juwon Oh, Rashid Ali, Jung Su Park, Dongho Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Significant changes of macrocyclic aromaticity in expanded porphyrins through C₆₀ complexation were studied by ¹H NMR spectroscopy and nucleus-independent chemical shift calculations. This work is a detailed research study of how the formation of a complex of dual aromatic expanded porphyrin with fullerene affects the electron densities in the main conjugation pathways and meso-substituents. Furthermore, we found that the formation of the photoinduced charge-separated state and the triplet excited-state populations of the bowl-shaped and rigid expanded porphyrin can be controlled by a simple complexation with C₆₀.

Original language	English
Pages (from-to)	8301-8304
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	57
DOIs	https://doi.org/10.1039/c9cc03928g
State	Published - 2019

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title = "Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C60",

abstract = "Significant changes of macrocyclic aromaticity in expanded porphyrins through C60 complexation were studied by 1H NMR spectroscopy and nucleus-independent chemical shift calculations. This work is a detailed research study of how the formation of a complex of dual aromatic expanded porphyrin with fullerene affects the electron densities in the main conjugation pathways and meso-substituents. Furthermore, we found that the formation of the photoinduced charge-separated state and the triplet excited-state populations of the bowl-shaped and rigid expanded porphyrin can be controlled by a simple complexation with C60.",

author = "Cha, \{Won Young\} and Ahreum Ahn and Taeyeon Kim and Juwon Oh and Rashid Ali and Park, \{Jung Su\} and Dongho Kim",

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year = "2019",

doi = "10.1039/c9cc03928g",

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T1 - Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C60

AU - Cha, Won Young

AU - Ahn, Ahreum

AU - Kim, Taeyeon

AU - Oh, Juwon

AU - Ali, Rashid

AU - Park, Jung Su

AU - Kim, Dongho

PY - 2019

Y1 - 2019

N2 - Significant changes of macrocyclic aromaticity in expanded porphyrins through C60 complexation were studied by 1H NMR spectroscopy and nucleus-independent chemical shift calculations. This work is a detailed research study of how the formation of a complex of dual aromatic expanded porphyrin with fullerene affects the electron densities in the main conjugation pathways and meso-substituents. Furthermore, we found that the formation of the photoinduced charge-separated state and the triplet excited-state populations of the bowl-shaped and rigid expanded porphyrin can be controlled by a simple complexation with C60.

AB - Significant changes of macrocyclic aromaticity in expanded porphyrins through C60 complexation were studied by 1H NMR spectroscopy and nucleus-independent chemical shift calculations. This work is a detailed research study of how the formation of a complex of dual aromatic expanded porphyrin with fullerene affects the electron densities in the main conjugation pathways and meso-substituents. Furthermore, we found that the formation of the photoinduced charge-separated state and the triplet excited-state populations of the bowl-shaped and rigid expanded porphyrin can be controlled by a simple complexation with C60.

UR - https://www.scopus.com/pages/publications/85068790393

U2 - 10.1039/c9cc03928g

DO - 10.1039/c9cc03928g

M3 - Article

C2 - 31250853

AN - SCOPUS:85068790393

SN - 1359-7345

VL - 55

SP - 8301

EP - 8304

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C₆₀

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