Characteristics of gas sensors based on single-walled carbon nanotube bundles treated by acid stirring

Hong Quang Nguyen, Shao Lin Zhang, Gi Hong Rue, Jeung Soo Huh

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

The paper presents the effect of acid treatment on the structure of single-walled carbon nanotube (SWNT) bundles and on the characteristics of SWNT-based gas sensors. The commercial SWNT powder was treated with a mixture of concentrated H2SO4:HNO3 (3:1 in volume) before used to fabricate sensors for ammonia (NH3) detection at room temperature. The Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM) images indicated that the acid treatment not only removed most of catalytic particles from the SWNT bundles, but also caused SWNT bundles to be fragile. The fracture of the SWNT facilitated for gas molecules to adsorb in the SWNT sites, leading to an enhancement in sensitivity of the sensors. Upon exposing to 50 ppm NH3 in 450 seem of nitrogen flowing rate at room temperature, the resistance of the 2-h-stirred sensors increased to 38% compared to 22% of the 1-h-stirred sensor. The recovery of the SWNT sensor was also accelerated owing to the treatment. These findings opened a new direction to improve the characteristics of SWNT-based gas sensors.

Original languageEnglish
Title of host publicationAdvances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia
PublisherTrans Tech Publications Ltd.
Pages1173-1176
Number of pages4
EditionPART 2
ISBN (Print)3908451310, 9783908451310
DOIs
StatePublished - 2007
EventIUMRS International Conference in Asia 2006, IUMRS-ICA 2006 - Jeju, Korea, Republic of
Duration: 10 Sep 200614 Sep 2006

Publication series

NameSolid State Phenomena
NumberPART 2
Volume124-126
ISSN (Print)1012-0394

Conference

ConferenceIUMRS International Conference in Asia 2006, IUMRS-ICA 2006
Country/TerritoryKorea, Republic of
CityJeju
Period10/09/0614/09/06

Keywords

  • Acid treatment
  • Carbon nanotube
  • Characteristics
  • Gas sensor
  • Sensitivity

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