Characterization of nitro-substituted polybenzimidazole synthesized by the reaction with nitric acid

Jin Hyun Choi, Won Seok Lyoo, Wan Shik Ha, Volker Rossbach

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2 Scopus citations

Abstract

Nitro-substituted poly [2,2’ -(m-phenylene)-5,5-bibenzimidazole]s (PBIs) were synthesized by the reaction of PBI with nitric acid in sulfuric acid under various conditions. The number of nitro groups substituted on the aromatic ring of PBI per polymeric unit varied from 1.44 to 3.55 according to the reaction conditions. An increase in reaction temperature and concentration of the nitric acid increased the degree of substitution. The inherent viscosity of the substituted polymer increased as the reaction temperature decreased. When the reaction temperature was 30°C, the inherent viscosity of the polymer increased as the concentration of nitric acid increased. The nitro-substituted PBI exhibited polyelectrolyte behavior in formic acid. The nitro groups substituted on PBI were dissociated when the polymer was heated to 450°C, displaying exothermic behavior, and the decomposition of polymer was proportional to its nitro group content. All nitro-substituted PBIs showed better solubilities in polar aprotic and acidic solvents, such as dimethylacetamide, dimethylsulfoxide, dimethylformamide, N-methylpyrrolidone, formic acid, sulfuric acid, and trifluoromethanesulfonic acid.

Original languageEnglish
Pages (from-to)1875-1891
Number of pages17
JournalJournal of Macromolecular Science - Pure and Applied Chemistry
Volume32
Issue number11
DOIs
StatePublished - 1995

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