Characterization of petroleum by high resolution field desorption/ionization and atmospheric pressure photoionization FT-ICR mass spectrometry

Alan G. Marshall; Sunghwan Kim; Jeremiah M. Purcell; Tanner M. Schaub; Donald F. Smith; Ryan P. Rodgers

Characterization of petroleum by high resolution field desorption/ionization and atmospheric pressure photoionization FT-ICR mass spectrometry

Alan G. Marshall, Sunghwan Kim, Jeremiah M. Purcell, Tanner M. Schaub, Donald F. Smith, Ryan P. Rodgers

National High Magnetic Field Laboratory

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

FT-ICR MS analysis of crude oil achieves sufficient mass resolving power and high mass accuracy to allow for the baseline resolution and elemental composition assignment of thousands of heteroatomic species in a single crude oil. Electrospray ionization was limited to polar species that are readily protonated or deprotonated. Two other ionization methods (FD and APPI) were coupled to probe the much larger fraction of nonpolars (e.g., aromatic hydrocarbons and thiophenes), illustrated for the aromatic fraction of a heavy crude. FD produced even-electron ions, while APPI produced even- and odd-electron ions. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

Original language	English
Pages (from-to)	FUEL-94
Journal	ACS National Meeting Book of Abstracts
Volume	229
Issue number	1
State	Published - 2005
Event	229th ACS National Meeting - San Diego, CA., United States Duration: 13 Mar 2005 → 17 Mar 2005

Cite this

@article{62dcb254cac443d6b28037b3591420d0,

title = "Characterization of petroleum by high resolution field desorption/ionization and atmospheric pressure photoionization FT-ICR mass spectrometry",

abstract = "FT-ICR MS analysis of crude oil achieves sufficient mass resolving power and high mass accuracy to allow for the baseline resolution and elemental composition assignment of thousands of heteroatomic species in a single crude oil. Electrospray ionization was limited to polar species that are readily protonated or deprotonated. Two other ionization methods (FD and APPI) were coupled to probe the much larger fraction of nonpolars (e.g., aromatic hydrocarbons and thiophenes), illustrated for the aromatic fraction of a heavy crude. FD produced even-electron ions, while APPI produced even- and odd-electron ions. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).",

author = "Marshall, {Alan G.} and Sunghwan Kim and Purcell, {Jeremiah M.} and Schaub, {Tanner M.} and Smith, {Donald F.} and Rodgers, {Ryan P.}",

year = "2005",

language = "English",

volume = "229",

pages = "FUEL--94",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

number = "1",

note = "229th ACS National Meeting ; Conference date: 13-03-2005 Through 17-03-2005",

}

TY - JOUR

T1 - Characterization of petroleum by high resolution field desorption/ionization and atmospheric pressure photoionization FT-ICR mass spectrometry

AU - Marshall, Alan G.

AU - Kim, Sunghwan

AU - Purcell, Jeremiah M.

AU - Schaub, Tanner M.

AU - Smith, Donald F.

AU - Rodgers, Ryan P.

PY - 2005

Y1 - 2005

N2 - FT-ICR MS analysis of crude oil achieves sufficient mass resolving power and high mass accuracy to allow for the baseline resolution and elemental composition assignment of thousands of heteroatomic species in a single crude oil. Electrospray ionization was limited to polar species that are readily protonated or deprotonated. Two other ionization methods (FD and APPI) were coupled to probe the much larger fraction of nonpolars (e.g., aromatic hydrocarbons and thiophenes), illustrated for the aromatic fraction of a heavy crude. FD produced even-electron ions, while APPI produced even- and odd-electron ions. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

AB - FT-ICR MS analysis of crude oil achieves sufficient mass resolving power and high mass accuracy to allow for the baseline resolution and elemental composition assignment of thousands of heteroatomic species in a single crude oil. Electrospray ionization was limited to polar species that are readily protonated or deprotonated. Two other ionization methods (FD and APPI) were coupled to probe the much larger fraction of nonpolars (e.g., aromatic hydrocarbons and thiophenes), illustrated for the aromatic fraction of a heavy crude. FD produced even-electron ions, while APPI produced even- and odd-electron ions. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

UR - http://www.scopus.com/inward/record.url?scp=22744455141&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:22744455141

SN - 0065-7727

VL - 229

SP - FUEL-94

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

IS - 1

T2 - 229th ACS National Meeting

Y2 - 13 March 2005 through 17 March 2005

ER -

Characterization of petroleum by high resolution field desorption/ionization and atmospheric pressure photoionization FT-ICR mass spectrometry

Abstract

Other files and links

Fingerprint

Cite this