Chromogenic detection of hydrogen sulfide using squarylium-based chemosensors

Ha Lim Noh; Byeong M. Oh; Young Ki Park; Hye W. Chun; Junyeop Lee; Jae Keon Kim; Jian Zheng; Daewoong Jung; Woosung Lee; Jong H. Kim

doi:10.1016/j.saa.2020.118457

Chromogenic detection of hydrogen sulfide using squarylium-based chemosensors

Ha Lim Noh, Byeong M. Oh, Young Ki Park, Hye W. Chun, Junyeop Lee, Jae Keon Kim, Jian Zheng, Daewoong Jung, Woosung Lee, Jong H. Kim

School of Textile Engineering & Fashion Design

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Squarylium-based colorimetric hydrogen sulfide (H₂S) chemosensors (SQ1, SQ2, and SQ3) were developed, and their detection properties were systematically characterized. SQ1 exhibited rapid and high resolution H₂S sensing properties through significant color changes detectable by naked-eye with limit of detection as low as 7.2 ppb. SQ1 also showed excellent selectivity for H₂S detection over other relevant anions and nucleophiles. Sensing mechanisms of SQ1 were investigated based on spectroscopic and ¹H NMR analyses with quantum calculations. Furthermore, SQ1 showed an efficient response to H2S under versatile conditions in the solution, solid, and dyed fabric states, which suggests applicability of SQ1 to simple, low-cost, and practical H₂S sensors.

Original language	English
Article number	118457
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	239
DOIs	https://doi.org/10.1016/j.saa.2020.118457
State	Published - 5 Oct 2020

Keywords

Colorimetric chemosensor
Hydrogen sulfide
Selectivity
Spectroscopic characterization
Squarylium derivative

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10.1016/j.saa.2020.118457

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title = "Chromogenic detection of hydrogen sulfide using squarylium-based chemosensors",

abstract = "Squarylium-based colorimetric hydrogen sulfide (H2S) chemosensors (SQ1, SQ2, and SQ3) were developed, and their detection properties were systematically characterized. SQ1 exhibited rapid and high resolution H2S sensing properties through significant color changes detectable by naked-eye with limit of detection as low as 7.2 ppb. SQ1 also showed excellent selectivity for H2S detection over other relevant anions and nucleophiles. Sensing mechanisms of SQ1 were investigated based on spectroscopic and 1H NMR analyses with quantum calculations. Furthermore, SQ1 showed an efficient response to H2S under versatile conditions in the solution, solid, and dyed fabric states, which suggests applicability of SQ1 to simple, low-cost, and practical H2S sensors.",

keywords = "Colorimetric chemosensor, Hydrogen sulfide, Selectivity, Spectroscopic characterization, Squarylium derivative",

author = "Noh, \{Ha Lim\} and Oh, \{Byeong M.\} and Park, \{Young Ki\} and Chun, \{Hye W.\} and Junyeop Lee and Kim, \{Jae Keon\} and Jian Zheng and Daewoong Jung and Woosung Lee and Kim, \{Jong H.\}",

note = "Publisher Copyright: {\textcopyright} 2020",

year = "2020",

month = oct,

day = "5",

doi = "10.1016/j.saa.2020.118457",

language = "English",

volume = "239",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Chromogenic detection of hydrogen sulfide using squarylium-based chemosensors

AU - Noh, Ha Lim

AU - Oh, Byeong M.

AU - Park, Young Ki

AU - Chun, Hye W.

AU - Lee, Junyeop

AU - Kim, Jae Keon

AU - Zheng, Jian

AU - Jung, Daewoong

AU - Lee, Woosung

AU - Kim, Jong H.

PY - 2020/10/5

Y1 - 2020/10/5

N2 - Squarylium-based colorimetric hydrogen sulfide (H2S) chemosensors (SQ1, SQ2, and SQ3) were developed, and their detection properties were systematically characterized. SQ1 exhibited rapid and high resolution H2S sensing properties through significant color changes detectable by naked-eye with limit of detection as low as 7.2 ppb. SQ1 also showed excellent selectivity for H2S detection over other relevant anions and nucleophiles. Sensing mechanisms of SQ1 were investigated based on spectroscopic and 1H NMR analyses with quantum calculations. Furthermore, SQ1 showed an efficient response to H2S under versatile conditions in the solution, solid, and dyed fabric states, which suggests applicability of SQ1 to simple, low-cost, and practical H2S sensors.

AB - Squarylium-based colorimetric hydrogen sulfide (H2S) chemosensors (SQ1, SQ2, and SQ3) were developed, and their detection properties were systematically characterized. SQ1 exhibited rapid and high resolution H2S sensing properties through significant color changes detectable by naked-eye with limit of detection as low as 7.2 ppb. SQ1 also showed excellent selectivity for H2S detection over other relevant anions and nucleophiles. Sensing mechanisms of SQ1 were investigated based on spectroscopic and 1H NMR analyses with quantum calculations. Furthermore, SQ1 showed an efficient response to H2S under versatile conditions in the solution, solid, and dyed fabric states, which suggests applicability of SQ1 to simple, low-cost, and practical H2S sensors.

KW - Colorimetric chemosensor

KW - Hydrogen sulfide

KW - Selectivity

KW - Spectroscopic characterization

KW - Squarylium derivative

UR - https://www.scopus.com/pages/publications/85084952800

U2 - 10.1016/j.saa.2020.118457

DO - 10.1016/j.saa.2020.118457

M3 - Article

C2 - 32450535

AN - SCOPUS:85084952800

SN - 1386-1425

VL - 239

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

M1 - 118457

ER -

Chromogenic detection of hydrogen sulfide using squarylium-based chemosensors

Abstract

Keywords

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