TY - JOUR
T1 - Concentration Dependence Orange Light Generation Through Sm3+-Doped Soda Lime Alumino Borate Glasses for Orange Laser Medium Material
AU - Jarucha, Nawarut
AU - Ruangtaweep, Yotsakit
AU - Meejitpaisan, Piyachat
AU - Kim, Hong Joo
AU - Boontueng, Phongnared
AU - Kobdaj, Chinorat
AU - Ritjoho, Narongrit
AU - Sanghangthum, Taweap
AU - Valiev, Damir
AU - Kaewkhao, Jakrapong
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024
Y1 - 2024
N2 - The melt-quenching technique is used to fabricate calcium sodium aluminum borate glasses (Sm: ANCB) doped with varying concentrations of Sm3+ ions. Characteristics of ANCBSm glasses, including density, molar volume, refractive index, absorption, emission (via visible light, X-ray, and proton excitation), decay time, and CIE color coordinates, are analyzed. The density, molar volume, and refractive index of ANCBSm glass increased with Sm2O3 concentration. Sm3+ ions enabled photon absorption in both visible and NIR regions, with a strong reddish-orange emission at 600 nm due to the 6H5/2 → 6P3/2 transition under various excitations. X-ray excitation is also compared with BGO scintillation crystals. The J–O theory predicted the radiative properties of Sm3+ ion emission levels. Decay curves of the 6H5/2 levels showed a single exponential nature with a millisecond-order lifetime. CIE chromaticity of ANCBSm glasses is in the reddish-orange region. ANCBSm glasses have potential applications in orange laser medium material.
AB - The melt-quenching technique is used to fabricate calcium sodium aluminum borate glasses (Sm: ANCB) doped with varying concentrations of Sm3+ ions. Characteristics of ANCBSm glasses, including density, molar volume, refractive index, absorption, emission (via visible light, X-ray, and proton excitation), decay time, and CIE color coordinates, are analyzed. The density, molar volume, and refractive index of ANCBSm glass increased with Sm2O3 concentration. Sm3+ ions enabled photon absorption in both visible and NIR regions, with a strong reddish-orange emission at 600 nm due to the 6H5/2 → 6P3/2 transition under various excitations. X-ray excitation is also compared with BGO scintillation crystals. The J–O theory predicted the radiative properties of Sm3+ ion emission levels. Decay curves of the 6H5/2 levels showed a single exponential nature with a millisecond-order lifetime. CIE chromaticity of ANCBSm glasses is in the reddish-orange region. ANCBSm glasses have potential applications in orange laser medium material.
KW - BGO
KW - borate glasses
KW - luminescence
KW - samarium
KW - scintillator
UR - http://www.scopus.com/inward/record.url?scp=85197663478&partnerID=8YFLogxK
U2 - 10.1002/pssa.202400174
DO - 10.1002/pssa.202400174
M3 - Article
AN - SCOPUS:85197663478
SN - 1862-6300
JO - Physica Status Solidi (A) Applications and Materials Science
JF - Physica Status Solidi (A) Applications and Materials Science
ER -