Construction and characterization of novel molecular architectures through coordination-driven self-assembly: Rhomboid and overlapped double rhomboid

Jeum Jong Kim; Ock Keum Kwak; Jong Keun Park; Kil Sik Min; Yong Jin Yoon

doi:10.1007/s10847-013-0373-3

Construction and characterization of novel molecular architectures through coordination-driven self-assembly: Rhomboid and overlapped double rhomboid

Jeum Jong Kim
, Ock Keum Kwak
, Jong Keun Park
, Kil Sik Min
, Yong Jin Yoon

Department of Chemical Science Education

Electronics and Telecommunications Research Institute
Gyeongsang National University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt ₃)₂(NO₃)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.

Original language	English
Pages (from-to)	495-502
Number of pages	8
Journal	Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume	79
Issue number	3-4
DOIs	https://doi.org/10.1007/s10847-013-0373-3
State	Published - Aug 2014

Keywords

Ligand
Molecular architecture
Platinum
Rhomboid
Self-assembly
Supramolecule

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10.1007/s10847-013-0373-3

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title = "Construction and characterization of novel molecular architectures through coordination-driven self-assembly: Rhomboid and overlapped double rhomboid",

abstract = "The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt 3)2(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.",

keywords = "Ligand, Molecular architecture, Platinum, Rhomboid, Self-assembly, Supramolecule",

author = "Kim, \{Jeum Jong\} and Kwak, \{Ock Keum\} and Park, \{Jong Keun\} and Min, \{Kil Sik\} and Yoon, \{Yong Jin\}",

year = "2014",

month = aug,

doi = "10.1007/s10847-013-0373-3",

language = "English",

volume = "79",

pages = "495--502",

journal = "Journal of Inclusion Phenomena and Molecular Recognition in Chemistry",

issn = "0923-0750",

publisher = "Editura Stiintifica F. M. R.",

number = "3-4",

}

Construction and characterization of novel molecular architectures through coordination-driven self-assembly: Rhomboid and overlapped double rhomboid. / Kim, Jeum Jong; Kwak, Ock Keum; Park, Jong Keun et al.
In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 79, No. 3-4, 08.2014, p. 495-502.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Construction and characterization of novel molecular architectures through coordination-driven self-assembly

T2 - Rhomboid and overlapped double rhomboid

AU - Kim, Jeum Jong

AU - Kwak, Ock Keum

AU - Park, Jong Keun

AU - Min, Kil Sik

AU - Yoon, Yong Jin

PY - 2014/8

Y1 - 2014/8

N2 - The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt 3)2(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.

AB - The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt 3)2(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies.

KW - Ligand

KW - Molecular architecture

KW - Platinum

KW - Rhomboid

KW - Self-assembly

KW - Supramolecule

UR - https://www.scopus.com/pages/publications/84904209291

U2 - 10.1007/s10847-013-0373-3

DO - 10.1007/s10847-013-0373-3

M3 - Article

AN - SCOPUS:84904209291

SN - 0923-0750

VL - 79

SP - 495

EP - 502

JO - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

JF - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

IS - 3-4

ER -

Construction and characterization of novel molecular architectures through coordination-driven self-assembly: Rhomboid and overlapped double rhomboid

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Keywords

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