Construction of multi-N-heterocycle-containing organic solvent-soluble polymers with 1,3,4,6,9b-pentaazaphenalene

Hyeonuk Yeo, Masataka Hirose, Kazuo Tanaka, Yoshiki Chujo

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Multi-N-heterocycles could be a useful platform for constructing network structures via hydrogen bonds and for realizing catalyzed organic reactions. In addition, unique optical properties can be achieved by their incorporation into polymers. In this manuscript, the synthesis and characterization of an organic solvent-soluble polymer containing 1,3,4,6,9b-pentaazaphenalene are presented. From a series of optical measurements and comparative studies with model compounds, we investigated the electronic structures of polymer main chains containing the azaphenalene unit.

Original languageEnglish
Pages (from-to)688-693
Number of pages6
JournalPolymer Journal
Volume46
Issue number10
DOIs
StatePublished - 1 Jan 2014

Keywords

  • Azaphenalene
  • N-heterocycles
  • π-conjugation

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