Correlation between dispersion properties of TiO 2 colloidal sols and photoelectric characteristics of TiO 2 films

Hyun Suk Jung, Sang Wook Lee, Jin Young Kim, Kug Sun Hong, Young Cheol Lee, Kyung Hyun Ko

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

TiO 2 film for use as dye-sensitized solar cell was prepared using the TiO 2 colloidal sols (unpeptized sol and peptized sol). The optical properties and photocurrent-voltage characteristics of the resultant films were investigated. The optical transmittance of TiO 2 thin film prepared from the peptized colloidal sol was over 90%, while that of TiO 2 film from the unpeptized sol was under 80%. The TiO 2 photoelectrode prepared from the peptized colloidal sol showed low photoelectric conversion efficiency (η), 1.30%, whereas the efficiency of photoelectrode from the unpeptized sol was 2.21%. The high optical transmittance and low conversion efficiency of TiO 2 film from the peptized sol are discussed in terms of dense microstructure due to the drying nature of well-dispersed colloidal sol.

Original languageEnglish
Pages (from-to)479-483
Number of pages5
JournalJournal of Colloid and Interface Science
Volume279
Issue number2
DOIs
StatePublished - 15 Nov 2004

Keywords

  • Dispersion
  • Dye-sensitized solar cell
  • Microstructure
  • Peptization
  • TiO

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