Coumarin-decorated Schiff base hydrolysis as an efficient driving force for the fluorescence detection of water in organic solvents

Won Young Kim; Hu Shi; Hyo Sung Jung; Daeheum Cho; Peter Verwilst; Jin Yong Lee; Jong Seung Kim

doi:10.1039/c6cc04285f

Coumarin-decorated Schiff base hydrolysis as an efficient driving force for the fluorescence detection of water in organic solvents

Won Young Kim, Hu Shi, Hyo Sung Jung, Daeheum Cho, Peter Verwilst, Jin Yong Lee, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

A coumarin based Schiff base was found to be an excellent indicator of moisture, via rapid in situ hydrolysis. A structure-relationship examination of a small library of Schiff bases revealed the critical importance of hydrogen bond acceptors in close proximity to the imine bond, and this observation was further supported by theoretical calculations as well as the solid state structure analysis. The most sensitive compound demonstrated a limit of detection and quantification of 0.18% and 0.54% v/v water in DMSO, respectively.

Original language	English
Pages (from-to)	8675-8678
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	56
DOIs	https://doi.org/10.1039/c6cc04285f
State	Published - 2016

Access to Document

10.1039/c6cc04285f

Cite this

@article{9f48ad1a8b714267bd309172cd40a236,

title = "Coumarin-decorated Schiff base hydrolysis as an efficient driving force for the fluorescence detection of water in organic solvents",

abstract = "A coumarin based Schiff base was found to be an excellent indicator of moisture, via rapid in situ hydrolysis. A structure-relationship examination of a small library of Schiff bases revealed the critical importance of hydrogen bond acceptors in close proximity to the imine bond, and this observation was further supported by theoretical calculations as well as the solid state structure analysis. The most sensitive compound demonstrated a limit of detection and quantification of 0.18% and 0.54% v/v water in DMSO, respectively.",

author = "Kim, {Won Young} and Hu Shi and Jung, {Hyo Sung} and Daeheum Cho and Peter Verwilst and Lee, {Jin Yong} and Kim, {Jong Seung}",

note = "Publisher Copyright: {\textcopyright} 2016 oyal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc04285f",

language = "English",

volume = "52",

pages = "8675--8678",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "56",

}

TY - JOUR

T1 - Coumarin-decorated Schiff base hydrolysis as an efficient driving force for the fluorescence detection of water in organic solvents

AU - Kim, Won Young

AU - Shi, Hu

AU - Jung, Hyo Sung

AU - Cho, Daeheum

AU - Verwilst, Peter

AU - Lee, Jin Yong

AU - Kim, Jong Seung

PY - 2016

Y1 - 2016

N2 - A coumarin based Schiff base was found to be an excellent indicator of moisture, via rapid in situ hydrolysis. A structure-relationship examination of a small library of Schiff bases revealed the critical importance of hydrogen bond acceptors in close proximity to the imine bond, and this observation was further supported by theoretical calculations as well as the solid state structure analysis. The most sensitive compound demonstrated a limit of detection and quantification of 0.18% and 0.54% v/v water in DMSO, respectively.

AB - A coumarin based Schiff base was found to be an excellent indicator of moisture, via rapid in situ hydrolysis. A structure-relationship examination of a small library of Schiff bases revealed the critical importance of hydrogen bond acceptors in close proximity to the imine bond, and this observation was further supported by theoretical calculations as well as the solid state structure analysis. The most sensitive compound demonstrated a limit of detection and quantification of 0.18% and 0.54% v/v water in DMSO, respectively.

UR - http://www.scopus.com/inward/record.url?scp=84977620267&partnerID=8YFLogxK

U2 - 10.1039/c6cc04285f

DO - 10.1039/c6cc04285f

M3 - Article

C2 - 27333263

AN - SCOPUS:84977620267

SN - 1359-7345

VL - 52

SP - 8675

EP - 8678

JO - Chemical Communications

JF - Chemical Communications

IS - 56

ER -

Coumarin-decorated Schiff base hydrolysis as an efficient driving force for the fluorescence detection of water in organic solvents

Abstract

Access to Document

Other files and links

Fingerprint

Cite this