Crystal growth and visible fluorescence and energy transfer features of Dy3+/RE3+ (RE = Tb, Eu)-codoped Y3Al5O12 crystals

Wen Li; Jiaxue Yang; Yan Wang; G. Lakshminarayana; Jianfu Li; Zhaojie Zhu; Zhenyu You; Chaoyang Tu; Dong Eun Lee; Jonghun Yoon; Taejoon Park

doi:10.1016/j.jlumin.2022.118864

Crystal growth and visible fluorescence and energy transfer features of Dy³⁺/RE³⁺ (RE = Tb, Eu)-codoped Y₃Al₅O₁₂ crystals

Wen Li
, Jiaxue Yang
, Yan Wang
, G. Lakshminarayana
, Jianfu Li
, Zhaojie Zhu
, Zhenyu You
, Chaoyang Tu
, Dong Eun Lee
, Jonghun Yoon
, Taejoon Park

School of Architecture

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

In this work, 4 at% Dy³⁺: YAG (Dy: YAG), 4 at% Dy³⁺/0.5 at% Tb: YAG (Dy/Tb: YAG), 4 at% Dy³⁺/0.5 at% Eu³⁺: YAG (Dy/Eu: YAG), 0.5 at% Tb: YAG (Tb: YAG), and 0.5 at% Eu³⁺: YAG (Eu: YAG) crystals have been synthesized by the Czochralski method. Optical absorption and luminescence spectra of Dy: YAG, Dy/Tb: YAG, and Dy/Eu: YAG crystals are contrasted and discussed. Through emission decay times of Dy³⁺: ⁴F_9/2 level in related crystals and the fluorescence spectra under different excitations, the energy transfer pathways between Dy³⁺ and Tb³⁺, and Dy³⁺ and Eu³⁺ ions are explored. Additionally, Judd-Ofelt analysis is performed to estimate distinct spectroscopic factors like radiative transition rates, fluorescence branching ratios, and radiative lifetimes.

Original language	English
Article number	118864
Journal	Journal of Luminescence
Volume	247
DOIs	https://doi.org/10.1016/j.jlumin.2022.118864
State	Published - Jul 2022

Keywords

Dy/Eu
Dy/Tb
Energy transfer
Fluorescence features
YAG
Yellow laser crystal

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10.1016/j.jlumin.2022.118864

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@article{a2b51b06a12d4057bd1df092c5d5b4bc,

title = "Crystal growth and visible fluorescence and energy transfer features of Dy3+/RE3+ (RE = Tb, Eu)-codoped Y3Al5O12 crystals",

abstract = "In this work, 4 at\% Dy3+: YAG (Dy: YAG), 4 at\% Dy3+/0.5 at\% Tb: YAG (Dy/Tb: YAG), 4 at\% Dy3+/0.5 at\% Eu3+: YAG (Dy/Eu: YAG), 0.5 at\% Tb: YAG (Tb: YAG), and 0.5 at\% Eu3+: YAG (Eu: YAG) crystals have been synthesized by the Czochralski method. Optical absorption and luminescence spectra of Dy: YAG, Dy/Tb: YAG, and Dy/Eu: YAG crystals are contrasted and discussed. Through emission decay times of Dy3+: 4F9/2 level in related crystals and the fluorescence spectra under different excitations, the energy transfer pathways between Dy3+ and Tb3+, and Dy3+ and Eu3+ ions are explored. Additionally, Judd-Ofelt analysis is performed to estimate distinct spectroscopic factors like radiative transition rates, fluorescence branching ratios, and radiative lifetimes.",

keywords = "Dy/Eu, Dy/Tb, Energy transfer, Fluorescence features, YAG, Yellow laser crystal",

author = "Wen Li and Jiaxue Yang and Yan Wang and G. Lakshminarayana and Jianfu Li and Zhaojie Zhu and Zhenyu You and Chaoyang Tu and Lee, \{Dong Eun\} and Jonghun Yoon and Taejoon Park",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = jul,

doi = "10.1016/j.jlumin.2022.118864",

language = "English",

volume = "247",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Crystal growth and visible fluorescence and energy transfer features of Dy3+/RE3+ (RE = Tb, Eu)-codoped Y3Al5O12 crystals

AU - Li, Wen

AU - Yang, Jiaxue

AU - Wang, Yan

AU - Lakshminarayana, G.

AU - Li, Jianfu

AU - Zhu, Zhaojie

AU - You, Zhenyu

AU - Tu, Chaoyang

AU - Lee, Dong Eun

AU - Yoon, Jonghun

AU - Park, Taejoon

PY - 2022/7

Y1 - 2022/7

N2 - In this work, 4 at% Dy3+: YAG (Dy: YAG), 4 at% Dy3+/0.5 at% Tb: YAG (Dy/Tb: YAG), 4 at% Dy3+/0.5 at% Eu3+: YAG (Dy/Eu: YAG), 0.5 at% Tb: YAG (Tb: YAG), and 0.5 at% Eu3+: YAG (Eu: YAG) crystals have been synthesized by the Czochralski method. Optical absorption and luminescence spectra of Dy: YAG, Dy/Tb: YAG, and Dy/Eu: YAG crystals are contrasted and discussed. Through emission decay times of Dy3+: 4F9/2 level in related crystals and the fluorescence spectra under different excitations, the energy transfer pathways between Dy3+ and Tb3+, and Dy3+ and Eu3+ ions are explored. Additionally, Judd-Ofelt analysis is performed to estimate distinct spectroscopic factors like radiative transition rates, fluorescence branching ratios, and radiative lifetimes.

AB - In this work, 4 at% Dy3+: YAG (Dy: YAG), 4 at% Dy3+/0.5 at% Tb: YAG (Dy/Tb: YAG), 4 at% Dy3+/0.5 at% Eu3+: YAG (Dy/Eu: YAG), 0.5 at% Tb: YAG (Tb: YAG), and 0.5 at% Eu3+: YAG (Eu: YAG) crystals have been synthesized by the Czochralski method. Optical absorption and luminescence spectra of Dy: YAG, Dy/Tb: YAG, and Dy/Eu: YAG crystals are contrasted and discussed. Through emission decay times of Dy3+: 4F9/2 level in related crystals and the fluorescence spectra under different excitations, the energy transfer pathways between Dy3+ and Tb3+, and Dy3+ and Eu3+ ions are explored. Additionally, Judd-Ofelt analysis is performed to estimate distinct spectroscopic factors like radiative transition rates, fluorescence branching ratios, and radiative lifetimes.

KW - Dy/Eu

KW - Dy/Tb

KW - Energy transfer

KW - Fluorescence features

KW - YAG

KW - Yellow laser crystal

UR - https://www.scopus.com/pages/publications/85127147512

U2 - 10.1016/j.jlumin.2022.118864

DO - 10.1016/j.jlumin.2022.118864

M3 - Article

AN - SCOPUS:85127147512

SN - 0022-2313

VL - 247

JO - Journal of Luminescence

JF - Journal of Luminescence

M1 - 118864

ER -

Crystal growth and visible fluorescence and energy transfer features of Dy³⁺/RE³⁺ (RE = Tb, Eu)-codoped Y₃Al₅O₁₂ crystals

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Keywords

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