Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II)

Sankara Rao Rowthu; Jong Won Shin; Seung Hui Kim; Jong Jin Kim; Kil Sik Min

doi:10.1107/S1600536811021234

Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II)

Sankara Rao Rowthu, Jong Won Shin, Seung Hui Kim, Jong Jin Kim, Kil Sik Min

Department of Chemical Science Education

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the title compound, [Cu(N ₃) ₂(C ₂0H ₂₁N ₃)], the Cu ^II ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C - H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.

Original language	English
Pages (from-to)	m873-m874
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	7
DOIs	https://doi.org/10.1107/S1600536811021234
State	Published - Jul 2011

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title = "Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II)",

abstract = "In the title compound, [Cu(N 3) 2(C 20H 21N 3)], the Cu II ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C - H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.",

author = "Rowthu, {Sankara Rao} and Shin, {Jong Won} and Kim, {Seung Hui} and Kim, {Jong Jin} and Min, {Kil Sik}",

year = "2011",

month = jul,

doi = "10.1107/S1600536811021234",

language = "English",

volume = "67",

pages = "m873--m874",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

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TY - JOUR

T1 - Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II)

AU - Rowthu, Sankara Rao

AU - Shin, Jong Won

AU - Kim, Seung Hui

AU - Kim, Jong Jin

AU - Min, Kil Sik

PY - 2011/7

Y1 - 2011/7

N2 - In the title compound, [Cu(N 3) 2(C 20H 21N 3)], the Cu II ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C - H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.

AB - In the title compound, [Cu(N 3) 2(C 20H 21N 3)], the Cu II ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C - H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.

UR - http://www.scopus.com/inward/record.url?scp=79960037042&partnerID=8YFLogxK

U2 - 10.1107/S1600536811021234

DO - 10.1107/S1600536811021234

M3 - Article

AN - SCOPUS:79960037042

SN - 1600-5368

VL - 67

SP - m873-m874

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II)

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