TY - JOUR
T1 - Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl] aniline-κ2 N,N′}palladium(II)
AU - Nayab, Saira
AU - Lee, Hong In
AU - Jeong, Jong Hwa
PY - 2013/5
Y1 - 2013/5
N2 - In the title compound, [PdCl2(C17H28N 2)], the PdII atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the PdII atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd - N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd - Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N - H⋯Cl hydrogen bonds link molecules into discrete dimers.
AB - In the title compound, [PdCl2(C17H28N 2)], the PdII atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the PdII atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd - N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd - Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N - H⋯Cl hydrogen bonds link molecules into discrete dimers.
UR - http://www.scopus.com/inward/record.url?scp=84877304837&partnerID=8YFLogxK
U2 - 10.1107/S1600536813008271
DO - 10.1107/S1600536813008271
M3 - Article
AN - SCOPUS:84877304837
SN - 1600-5368
VL - 69
SP - m238-m239
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -