Dichlorido[(S)-N-(1-phenylethylidene)-1-(pyridin-2-yl)ethanamine- κ2 N,N′]zinc(II) dichloromethane solvate

Saira Nayab; Seung Min Paek; Jong Hwa Jeong

doi:10.1107/S1600536810029387

Dichlorido[(S)-N-(1-phenylethylidene)-1-(pyridin-2-yl)ethanamine- κ² N,N′]zinc(II) dichloromethane solvate

Saira Nayab, Seung Min Paek, Jong Hwa Jeong

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [ZnCl₂(C₁₅H₁₆N ₂)]·CH₂Cl₂, the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn - N and Zn - Cl bond lengths are 2.060 (4) Å and Zn - Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N - Zn - N and Cl - Zn - Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.

Original language	English
Pages (from-to)	m1027
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	8
DOIs	https://doi.org/10.1107/S1600536810029387
State	Published - Aug 2010

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title = "Dichlorido[(S)-N-(1-phenylethylidene)-1-(pyridin-2-yl)ethanamine- κ2 N,N′]zinc(II) dichloromethane solvate",

abstract = "In the title compound, [ZnCl2(C15H16N 2)]·CH2Cl2, the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn - N and Zn - Cl bond lengths are 2.060 (4) {\AA} and Zn - Cl = 2.179 (16) {\AA}, respectively]. The dihedral angle between the N - Zn - N and Cl - Zn - Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.",

author = "Saira Nayab and Paek, {Seung Min} and Jeong, {Jong Hwa}",

year = "2010",

month = aug,

doi = "10.1107/S1600536810029387",

language = "English",

volume = "66",

pages = "m1027",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Dichlorido[(S)-N-(1-phenylethylidene)-1-(pyridin-2-yl)ethanamine- κ2 N,N′]zinc(II) dichloromethane solvate

AU - Nayab, Saira

AU - Paek, Seung Min

AU - Jeong, Jong Hwa

PY - 2010/8

Y1 - 2010/8

N2 - In the title compound, [ZnCl2(C15H16N 2)]·CH2Cl2, the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn - N and Zn - Cl bond lengths are 2.060 (4) Å and Zn - Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N - Zn - N and Cl - Zn - Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.

AB - In the title compound, [ZnCl2(C15H16N 2)]·CH2Cl2, the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn - N and Zn - Cl bond lengths are 2.060 (4) Å and Zn - Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N - Zn - N and Cl - Zn - Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.

UR - http://www.scopus.com/inward/record.url?scp=77956836846&partnerID=8YFLogxK

U2 - 10.1107/S1600536810029387

DO - 10.1107/S1600536810029387

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SN - 1600-5368

VL - 66

SP - m1027

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Dichlorido[(S)-N-(1-phenylethylidene)-1-(pyridin-2-yl)ethanamine- κ² N,N′]zinc(II) dichloromethane solvate

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