Dissolution of Cellulosic Material with Glycol Ether/NaOH Aqueous Solution

Ji Ae Ryu, Kang Jae Kim, Eun Byeol Ahn, Tae Jin Eom

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The dissolution characteristics of glycol ether/NaOH solution were compared with NaOH/ urea and PEG/NaOH solutions were reported. With decreasing of the particle size and concentration of the cellulosic micro-fines (CMFs), the dissolution ability of the CMFs was drastically increased in all solvents. Compared with the PEG/NaOH solution, the glycol ether/NaOH solution had been found to exhibit a similar or higher regenerated cellulose degree of polymerization as well as solubility. The FT-IR analysis also identified the differences between natural cellulose and regenerated cellulose. The shortening of particle length in the filter paper non-dissolved part was observed through optical microscopy, and for CMFs, swelling were observed in most particles. These results confirmed that the properties of raw materials particle size and degree of polymerization had a significant effect on dissolution and the glycol ether/NaOH solutions was a new solvent.

Original languageEnglish
Pages (from-to)19-27
Number of pages9
JournalPalpu Chongi Gisul/Journal of Korea Technical Association of the Pulp and Paper Industry
Volume51
Issue number1
DOIs
StatePublished - 1 Jan 2019

Keywords

  • Cellulose micro-fines (cmfs)
  • Dissolution
  • Microwave organosolv
  • Naoh aqueous solution

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