Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration

Min Ren; Dawid Pinkowicz; Minyoung Yoon; Kimoon Kim; Li Min Zheng; Brian K. Breedlove; Masahiro Yamashita

doi:10.1021/ic400430q

Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration

Min Ren, Dawid Pinkowicz, Minyoung Yoon, Kimoon Kim, Li Min Zheng, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.

Original language	English
Pages (from-to)	8342-8348
Number of pages	7
Journal	Inorganic Chemistry
Volume	52
Issue number	15
DOIs	https://doi.org/10.1021/ic400430q
State	Published - 5 Aug 2013

Access to Document

10.1021/ic400430q

Cite this

@article{d62a99bebd8d41b5b974925d750fe6a0,

title = "Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration",

abstract = "A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.",

author = "Min Ren and Dawid Pinkowicz and Minyoung Yoon and Kimoon Kim and Zheng, {Li Min} and Breedlove, {Brian K.} and Masahiro Yamashita",

year = "2013",

month = aug,

day = "5",

doi = "10.1021/ic400430q",

language = "English",

volume = "52",

pages = "8342--8348",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration

AU - Ren, Min

AU - Pinkowicz, Dawid

AU - Yoon, Minyoung

AU - Kim, Kimoon

AU - Zheng, Li Min

AU - Breedlove, Brian K.

AU - Yamashita, Masahiro

PY - 2013/8/5

Y1 - 2013/8/5

N2 - A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.

AB - A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.

UR - http://www.scopus.com/inward/record.url?scp=84881149682&partnerID=8YFLogxK

U2 - 10.1021/ic400430q

DO - 10.1021/ic400430q

M3 - Article

AN - SCOPUS:84881149682

SN - 0020-1669

VL - 52

SP - 8342

EP - 8348

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration

Abstract

Access to Document

Other files and links

Fingerprint

Cite this