Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst

Do Young Hong; Jong San Chang; Ji Hye Lee; Vladislav P. Vislovskiy; Sung Hwa Jhung; Sang Eon Park; Yeung Ho Park

doi:10.1016/j.cattod.2005.11.038

Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst

Do Young Hong, Jong San Chang, Ji Hye Lee, Vladislav P. Vislovskiy, Sung Hwa Jhung, Sang Eon Park, Yeung Ho Park

Research output: Contribution to journal › Conference article › peer-review

16 Scopus citations

Abstract

The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen and carbon dioxide as diluent or oxidant. Among them, the addition of CO₂ gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable catalytic performance. Carbon dioxide plays a beneficial role as a selective oxidant in improving the catalytic behavior through the oxidative pathway.

Original language	English
Pages (from-to)	86-88
Number of pages	3
Journal	Catalysis Today
Volume	112
Issue number	1-4
DOIs	https://doi.org/10.1016/j.cattod.2005.11.038
State	Published - 15 Mar 2006

Keywords

Carbon dioxide
Dehydrogenation
Ethylbenzene
Oxidant
Styrene
Supported vanadium-antimony oxide catalyst

Access to Document

10.1016/j.cattod.2005.11.038

Cite this

@article{4e5fc52a90fb46599fd6266229b0624b,

title = "Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst",

abstract = "The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen and carbon dioxide as diluent or oxidant. Among them, the addition of CO2 gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable catalytic performance. Carbon dioxide plays a beneficial role as a selective oxidant in improving the catalytic behavior through the oxidative pathway.",

keywords = "Carbon dioxide, Dehydrogenation, Ethylbenzene, Oxidant, Styrene, Supported vanadium-antimony oxide catalyst",

author = "Hong, {Do Young} and Chang, {Jong San} and Lee, {Ji Hye} and Vislovskiy, {Vladislav P.} and Jhung, {Sung Hwa} and Park, {Sang Eon} and Park, {Yeung Ho}",

year = "2006",

month = mar,

day = "15",

doi = "10.1016/j.cattod.2005.11.038",

language = "English",

volume = "112",

pages = "86--88",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier B.V.",

number = "1-4",

}

TY - JOUR

T1 - Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst

AU - Hong, Do Young

AU - Chang, Jong San

AU - Lee, Ji Hye

AU - Vislovskiy, Vladislav P.

AU - Jhung, Sung Hwa

AU - Park, Sang Eon

AU - Park, Yeung Ho

PY - 2006/3/15

Y1 - 2006/3/15

N2 - The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen and carbon dioxide as diluent or oxidant. Among them, the addition of CO2 gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable catalytic performance. Carbon dioxide plays a beneficial role as a selective oxidant in improving the catalytic behavior through the oxidative pathway.

AB - The dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst has been studied under different atmospheres such as inert nitrogen, steam, oxygen and carbon dioxide as diluent or oxidant. Among them, the addition of CO2 gave the highest styrene yield (up to 82%) and styrene selectivity (up to 97%) along with stable catalytic performance. Carbon dioxide plays a beneficial role as a selective oxidant in improving the catalytic behavior through the oxidative pathway.

KW - Carbon dioxide

KW - Dehydrogenation

KW - Ethylbenzene

KW - Oxidant

KW - Styrene

KW - Supported vanadium-antimony oxide catalyst

UR - http://www.scopus.com/inward/record.url?scp=32544447884&partnerID=8YFLogxK

U2 - 10.1016/j.cattod.2005.11.038

DO - 10.1016/j.cattod.2005.11.038

M3 - Conference article

AN - SCOPUS:32544447884

SN - 0920-5861

VL - 112

SP - 86

EP - 88

JO - Catalysis Today

JF - Catalysis Today

IS - 1-4

ER -

Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium-antimony oxide catalyst

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this