Effect of Heat Treatment Temperature on the Crystallization Behavior and Microstructural Evolution of Amorphous NbCo1.1Sn

Chanwon Jung, Siyuan Zhang, Kyuseon Jang, Ningyan Cheng, Christina Scheu, Seong Hoon Yi, Pyuck Pa Choi

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Heat treatment-induced nanocrystallization of amorphous precursors is a promising method for nanostructuring half-Heusler compounds as it holds significant potential in the fabrication of intricate and customizable nanostructured materials. To fully exploit these advantages, a comprehensive understanding of the crystallization behavior of amorphous precursors under different crystallization conditions is crucial. In this study, we investigated the crystallization behavior of the amorphous NbCo1.1Sn alloy at elevated temperatures (783 and 893 K) using transmission electron microscopy and atom probe tomography. As a result, heat treatment at 893 K resulted in a significantly finer grain structure than heat treatment at 783 K owing to the higher nucleation rate at 893 K. At both temperatures, the predominant phase was a half-Heusler phase, whereas the Heusler phase, associated with Co diffusion, was exclusively observed at the specimen annealed at 893 K. The Debye-Callaway model supports that the lower lattice thermal conductivity of NbCo1.1Sn annealed at 893 K is primarily attributed to the formation of Heusler nanoprecipitates rather than a finer grain size. The experimental findings of this study provide valuable insights into the nanocrystallization of amorphous alloys for enhancing thermoelectric properties.

Original languageEnglish
Pages (from-to)46064-46073
Number of pages10
JournalACS Applied Materials and Interfaces
Volume15
Issue number39
DOIs
StatePublished - 4 Oct 2023

Keywords

  • amorphous
  • atom probe tomography
  • crystallization
  • diffusion
  • half-Heusler compounds
  • transmission electron microscopy

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