Effect of incorporation of sulfonate (–SO                         3                                                                              -                         ) on surface sealing of polystyrene (PS)-based bowl

Jin Ho Son; Da In Kim; Ju Hyang Park; Hojun Seo; Sang Gi Hong; Ji Hyun Choi; Jongbok Kim; Geon Dae Moon; Dong Choon Hyun

doi:10.1016/j.polymer.2019.01.072

Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl

Jin Ho Son, Da In Kim, Ju Hyang Park, Hojun Seo, Sang Gi Hong, Ji Hyun Choi, Jongbok Kim, Geon Dae Moon, Dong Choon Hyun

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

We study thermal annealing-driven surface sealing of polymer hollow particles with a different surface property. Use of phase separation between polystyrene (PS) solid particles incorporated with sulfonate (–SO ₃ ^- ) group and decane allows their transformation into hollow particles with an opening on the surface. Control of the phase separation enables us to tune the structure (outer and inner diameters, and size of the opening) of the hollow particles. While thermally annealed at a temperature above T _g of the polymer, structural change of the hollow particles is experimentally observed and theoretically analyzed. The results demonstrate that the change in the surface property of the hollow particles due to the incorporation of the –SO ₃ ^- group can have a direct impact on their sealing behavior and surface-sealed structure.

Original language	English
Pages (from-to)	85-92
Number of pages	8
Journal	Polymer
Volume	167
DOIs	https://doi.org/10.1016/j.polymer.2019.01.072
State	Published - 22 Mar 2019

Keywords

Hollow particle
Polymer interface
Polymer particle
Surface property
Surface sealing

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10.1016/j.polymer.2019.01.072

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Son, J. H., Kim, D. I., Park, J. H., Seo, H., Hong, S. G., Choi, J. H., Kim, J., Moon, G. D., & Hyun, D. C. (2019). Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl Polymer, 167, 85-92. https://doi.org/10.1016/j.polymer.2019.01.072

@article{0fb81d6ec40744d1a1ea86c3f0f056ea,

title = " Effect of incorporation of sulfonate (–SO 3 - ) on surface sealing of polystyrene (PS)-based bowl ",

abstract = " We study thermal annealing-driven surface sealing of polymer hollow particles with a different surface property. Use of phase separation between polystyrene (PS) solid particles incorporated with sulfonate (–SO 3 - ) group and decane allows their transformation into hollow particles with an opening on the surface. Control of the phase separation enables us to tune the structure (outer and inner diameters, and size of the opening) of the hollow particles. While thermally annealed at a temperature above T g of the polymer, structural change of the hollow particles is experimentally observed and theoretically analyzed. The results demonstrate that the change in the surface property of the hollow particles due to the incorporation of the –SO 3 - group can have a direct impact on their sealing behavior and surface-sealed structure.",

keywords = "Hollow particle, Polymer interface, Polymer particle, Surface property, Surface sealing",

author = "Son, {Jin Ho} and Kim, {Da In} and Park, {Ju Hyang} and Hojun Seo and Hong, {Sang Gi} and Choi, {Ji Hyun} and Jongbok Kim and Moon, {Geon Dae} and Hyun, {Dong Choon}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = mar,

day = "22",

doi = "10.1016/j.polymer.2019.01.072",

language = "English",

volume = "167",

pages = "85--92",

journal = "Polymer",

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publisher = "Elsevier B.V.",

}

Son, JH, Kim, DI, Park, JH, Seo, H, Hong, SG, Choi, JH, Kim, J, Moon, GD & Hyun, DC 2019, ' Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl ', Polymer, vol. 167, pp. 85-92. https://doi.org/10.1016/j.polymer.2019.01.072

Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl . / Son, Jin Ho; Kim, Da In; Park, Ju Hyang et al.
In: Polymer, Vol. 167, 22.03.2019, p. 85-92.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Effect of incorporation of sulfonate (–SO 3 - ) on surface sealing of polystyrene (PS)-based bowl

AU - Son, Jin Ho

AU - Kim, Da In

AU - Park, Ju Hyang

AU - Seo, Hojun

AU - Hong, Sang Gi

AU - Choi, Ji Hyun

AU - Kim, Jongbok

AU - Moon, Geon Dae

AU - Hyun, Dong Choon

PY - 2019/3/22

Y1 - 2019/3/22

N2 - We study thermal annealing-driven surface sealing of polymer hollow particles with a different surface property. Use of phase separation between polystyrene (PS) solid particles incorporated with sulfonate (–SO 3 - ) group and decane allows their transformation into hollow particles with an opening on the surface. Control of the phase separation enables us to tune the structure (outer and inner diameters, and size of the opening) of the hollow particles. While thermally annealed at a temperature above T g of the polymer, structural change of the hollow particles is experimentally observed and theoretically analyzed. The results demonstrate that the change in the surface property of the hollow particles due to the incorporation of the –SO 3 - group can have a direct impact on their sealing behavior and surface-sealed structure.

AB - We study thermal annealing-driven surface sealing of polymer hollow particles with a different surface property. Use of phase separation between polystyrene (PS) solid particles incorporated with sulfonate (–SO 3 - ) group and decane allows their transformation into hollow particles with an opening on the surface. Control of the phase separation enables us to tune the structure (outer and inner diameters, and size of the opening) of the hollow particles. While thermally annealed at a temperature above T g of the polymer, structural change of the hollow particles is experimentally observed and theoretically analyzed. The results demonstrate that the change in the surface property of the hollow particles due to the incorporation of the –SO 3 - group can have a direct impact on their sealing behavior and surface-sealed structure.

KW - Hollow particle

KW - Polymer interface

KW - Polymer particle

KW - Surface property

KW - Surface sealing

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U2 - 10.1016/j.polymer.2019.01.072

DO - 10.1016/j.polymer.2019.01.072

M3 - Article

AN - SCOPUS:85061343617

SN - 0032-3861

VL - 167

SP - 85

EP - 92

JO - Polymer

JF - Polymer

ER -

Son JH, Kim DI, Park JH, Seo H, Hong SG, Choi JH et al. Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl Polymer. 2019 Mar 22;167:85-92. doi: 10.1016/j.polymer.2019.01.072

Effect of incorporation of sulfonate (–SO ₃ ^- ) on surface sealing of polystyrene (PS)-based bowl

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Keywords

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