Effective radioactive strontium removal using lithium titanate decorated Ti₃C₂T_x MXene/polyacrylonitrile beads

A lithium titanate-decorated Ti₃C₂T_x MXene (LTO-MX) composite was synthesized through etching and alkali processes, and subsequently immobilized using polyacrylonitrile (PAN) polymer via a phase inversion method. In the batch study, the strontium adsorption behavior followed the Redlich-Peterson isotherm and the pseudo-second-order kinetic models. The maximum adsorption capacity for strontium reached 24.05 mg/g. Furthermore, a continuous fixed-bed column study was performed using the LTO-MX PAN beads to remove strontium from aqueous solutions. The dynamic behavior of column adsorption was examined under various operating parameters such as initial strontium concentration, flow rate, and bed height. Dynamic modeling was employed to describe adsorption breakthrough properties based on these experimental data. Both the Thomas and Yoon-Nelson models accurately simulated the breakthrough curves. The proposed mechanisms for strontium adsorption included encapsulation, electrostatic attraction, cation exchange, and surface complexation. These results demonstrate the effectiveness of LTO-MX PAN beads as adsorbents for the continuous removal of strontium from radioactive wastewater.