Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole

Thanh Tuan Bui; Adriana Iordache; Zhongrui Chen; Vladimir V. Roznyatovskiy; Eric Saint-Aman; Jong Min Lim; Byung Sun Lee; Sudip Ghosh; Jean Claude Moutet; Jonathan L. Sessler; Dongho Kim; Christophe Bucher

doi:10.1002/chem.201200196

Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole

Thanh Tuan Bui, Adriana Iordache, Zhongrui Chen, Vladimir V. Roznyatovskiy, Eric Saint-Aman, Jong Min Lim, Byung Sun Lee, Sudip Ghosh, Jean Claude Moutet, Jonathan L. Sessler, Dongho Kim, Christophe Bucher

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).

Original language	English
Pages (from-to)	5853-5859
Number of pages	7
Journal	Chemistry - A European Journal
Volume	18
Issue number	19
DOIs	https://doi.org/10.1002/chem.201200196
State	Published - 7 May 2012

Keywords

cyclo[n]pyrroles
electrochemical synthesis
NMR spectroscopy
phorphyrinoids
UV/Vis spectroscopy

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10.1002/chem.201200196

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title = "Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole",

abstract = "A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).",

keywords = "cyclo[n]pyrroles, electrochemical synthesis, NMR spectroscopy, phorphyrinoids, UV/Vis spectroscopy",

author = "Bui, {Thanh Tuan} and Adriana Iordache and Zhongrui Chen and Roznyatovskiy, {Vladimir V.} and Eric Saint-Aman and Lim, {Jong Min} and Lee, {Byung Sun} and Sudip Ghosh and Moutet, {Jean Claude} and Sessler, {Jonathan L.} and Dongho Kim and Christophe Bucher",

year = "2012",

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doi = "10.1002/chem.201200196",

language = "English",

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T1 - Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole

AU - Bui, Thanh Tuan

AU - Iordache, Adriana

AU - Chen, Zhongrui

AU - Roznyatovskiy, Vladimir V.

AU - Saint-Aman, Eric

AU - Lim, Jong Min

AU - Lee, Byung Sun

AU - Ghosh, Sudip

AU - Moutet, Jean Claude

AU - Sessler, Jonathan L.

AU - Kim, Dongho

AU - Bucher, Christophe

PY - 2012/5/7

Y1 - 2012/5/7

N2 - A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).

AB - A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).

KW - cyclo[n]pyrroles

KW - electrochemical synthesis

KW - NMR spectroscopy

KW - phorphyrinoids

KW - UV/Vis spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=84860703722&partnerID=8YFLogxK

U2 - 10.1002/chem.201200196

DO - 10.1002/chem.201200196

M3 - Article

AN - SCOPUS:84860703722

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SP - 5853

EP - 5859

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 19

ER -

Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole

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Keywords

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