Electroluminescent properties of an electrochemically cross-linkable carbazole peripheral poly(benzyl ether) dendrimer

Jin Young Park; Dong Eun Kim; Ramakrishna Ponnapati; Jong Min Kim; Young Soo Kwon; Rigoberto C. Advincula

doi:10.1002/cphc.201000785

Electroluminescent properties of an electrochemically cross-linkable carbazole peripheral poly(benzyl ether) dendrimer

Jin Young Park
, Dong Eun Kim
, Ramakrishna Ponnapati
, Jong Min Kim
, Young Soo Kwon
, Rigoberto C. Advincula

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The electroluminescent (EL) properties of a cross-linkable carbazole-terminated poly(benzyl ether) dendrimer, G₃-cbz DN, doped into a PVK:PBD host matrix with a double-layer device configuration are investigated. Different concentrations of the guest material can control device efficiency, related to chromaticity of white emission and the origin of excited-state complexes occurring between hole-transporting carbazole units (PVK or G₃-cbz DN) and electron-transporting oxadiazole (PBD). Two excited states (exciplex and electroplex) generated at the interfaces of PVK/G₃-cbz DN and PBD result in competitive emission, exhibiting a broad band in the EL spectra.

Original language	English
Pages (from-to)	1010-1015
Number of pages	6
Journal	ChemPhysChem
Volume	12
Issue number	5
DOIs	https://doi.org/10.1002/cphc.201000785
State	Published - 4 Apr 2011

Keywords

dendrimers
electrochemistry
electroplex
exciplex
luminescence

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10.1002/cphc.201000785

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title = "Electroluminescent properties of an electrochemically cross-linkable carbazole peripheral poly(benzyl ether) dendrimer",

abstract = "The electroluminescent (EL) properties of a cross-linkable carbazole-terminated poly(benzyl ether) dendrimer, G3-cbz DN, doped into a PVK:PBD host matrix with a double-layer device configuration are investigated. Different concentrations of the guest material can control device efficiency, related to chromaticity of white emission and the origin of excited-state complexes occurring between hole-transporting carbazole units (PVK or G3-cbz DN) and electron-transporting oxadiazole (PBD). Two excited states (exciplex and electroplex) generated at the interfaces of PVK/G3-cbz DN and PBD result in competitive emission, exhibiting a broad band in the EL spectra.",

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year = "2011",

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doi = "10.1002/cphc.201000785",

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T1 - Electroluminescent properties of an electrochemically cross-linkable carbazole peripheral poly(benzyl ether) dendrimer

AU - Park, Jin Young

AU - Kim, Dong Eun

AU - Ponnapati, Ramakrishna

AU - Kim, Jong Min

AU - Kwon, Young Soo

AU - Advincula, Rigoberto C.

PY - 2011/4/4

Y1 - 2011/4/4

N2 - The electroluminescent (EL) properties of a cross-linkable carbazole-terminated poly(benzyl ether) dendrimer, G3-cbz DN, doped into a PVK:PBD host matrix with a double-layer device configuration are investigated. Different concentrations of the guest material can control device efficiency, related to chromaticity of white emission and the origin of excited-state complexes occurring between hole-transporting carbazole units (PVK or G3-cbz DN) and electron-transporting oxadiazole (PBD). Two excited states (exciplex and electroplex) generated at the interfaces of PVK/G3-cbz DN and PBD result in competitive emission, exhibiting a broad band in the EL spectra.

AB - The electroluminescent (EL) properties of a cross-linkable carbazole-terminated poly(benzyl ether) dendrimer, G3-cbz DN, doped into a PVK:PBD host matrix with a double-layer device configuration are investigated. Different concentrations of the guest material can control device efficiency, related to chromaticity of white emission and the origin of excited-state complexes occurring between hole-transporting carbazole units (PVK or G3-cbz DN) and electron-transporting oxadiazole (PBD). Two excited states (exciplex and electroplex) generated at the interfaces of PVK/G3-cbz DN and PBD result in competitive emission, exhibiting a broad band in the EL spectra.

KW - dendrimers

KW - electrochemistry

KW - electroplex

KW - exciplex

KW - luminescence

UR - https://www.scopus.com/pages/publications/79953227725

U2 - 10.1002/cphc.201000785

DO - 10.1002/cphc.201000785

M3 - Article

AN - SCOPUS:79953227725

SN - 1439-4235

VL - 12

SP - 1010

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JO - ChemPhysChem

JF - ChemPhysChem

IS - 5

ER -

Electroluminescent properties of an electrochemically cross-linkable carbazole peripheral poly(benzyl ether) dendrimer

Abstract

Keywords

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