Etch characteristics of HfO 2 films on Si substrates

S. Norasetthekul, P. Y. Park, K. H. Baik, K. P. Lee, J. H. Shin, B. S. Jeong, V. Shishodia, D. P. Norton, S. J. Pearton

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52 Scopus citations

Abstract

The etch rates and mechanisms for HfO 2 thin films in Cl 2 -, SF 6 - or CH 4 /H 2 -based plasmas were measured as a function of source power, r.f. chuck power and discharge composition. Both Cl 2 - and SF 6 -based plasmas produced some degree of chemical enhancement in the etch mechanism. Selectivities between 0.2 and 5 were obtained for Si over HfO 2 in these two plasma chemistries. High fidelity pattern transfer was achieved for photoresist-masked HfO 2 /Si structures etched with Cl 2 /Ar over a broad range of pressures or with SF 6 /Ar at low pressures. The surface morphologies of both HfO 2 and Si were smooth over a wide range of etching conditions.

Original languageEnglish
Pages (from-to)75-81
Number of pages7
JournalApplied Surface Science
Volume187
Issue number1-2
DOIs
StatePublished - 14 Feb 2002

Keywords

  • Etch rates
  • HfO films
  • Plasma
  • Si substrates

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