Ethylene/norbornene copolymerization with iPr(Cp)(Flu)ZrCl2 catalyst: Effect of MAO cocatalyst and 3rd monomer

Keun Byoung Yoon; Yeon Seok Choi; Seok Kyun Noh; Dong Ho Lee

doi:10.1002/masy.200751405

Ethylene/norbornene copolymerization with iPr(Cp)(Flu)ZrCl₂ catalyst: Effect of MAO cocatalyst and 3^rd monomer

Keun Byoung Yoon, Yeon Seok Choi, Seok Kyun Noh, Dong Ho Lee

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The copolymerization of ethylene and norbomene (N) was carried out with iPr(Cp)(FIu)ZrCl₂ catalyst and modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity was dependent on the structure of MMAO, i.e., MMAO-4 exhibited higher catalyst activity than MMAO-3A containing more i-butyl groups. The glass transition temperature (Tg) and the composition of the produced copolymer were not affected by MMAO type. With styrene derivatives as 3^rd monomer, T_g of copolymer increased while the catalytic activity decreased. With the addition of 3^rd monomer, not only the content of 3rd monomer but also the content of N increased.

Original language	English
Pages (from-to)	27-33
Number of pages	7
Journal	Macromolecular Symposia
Volume	260
DOIs	https://doi.org/10.1002/masy.200751405
State	Published - 2007

Keywords

3 monomer
Ansa-metallocene catalyst
Copolymerization
Ethylene and norbornene
MMAO cocatalyst

Access to Document

10.1002/masy.200751405

Cite this

@article{7ebb540156a14c01b1846f7793dda048,

title = "Ethylene/norbornene copolymerization with iPr(Cp)(Flu)ZrCl2 catalyst: Effect of MAO cocatalyst and 3rd monomer",

abstract = "The copolymerization of ethylene and norbomene (N) was carried out with iPr(Cp)(FIu)ZrCl2 catalyst and modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity was dependent on the structure of MMAO, i.e., MMAO-4 exhibited higher catalyst activity than MMAO-3A containing more i-butyl groups. The glass transition temperature (Tg) and the composition of the produced copolymer were not affected by MMAO type. With styrene derivatives as 3rd monomer, Tg of copolymer increased while the catalytic activity decreased. With the addition of 3rd monomer, not only the content of 3rd monomer but also the content of N increased.",

keywords = "3 monomer, Ansa-metallocene catalyst, Copolymerization, Ethylene and norbornene, MMAO cocatalyst",

author = "Yoon, {Keun Byoung} and Choi, {Yeon Seok} and Noh, {Seok Kyun} and Lee, {Dong Ho}",

year = "2007",

doi = "10.1002/masy.200751405",

language = "English",

volume = "260",

pages = "27--33",

journal = "Macromolecular Symposia",

issn = "1022-1360",

publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Ethylene/norbornene copolymerization with iPr(Cp)(Flu)ZrCl2 catalyst

T2 - Effect of MAO cocatalyst and 3rd monomer

AU - Yoon, Keun Byoung

AU - Choi, Yeon Seok

AU - Noh, Seok Kyun

AU - Lee, Dong Ho

PY - 2007

Y1 - 2007

N2 - The copolymerization of ethylene and norbomene (N) was carried out with iPr(Cp)(FIu)ZrCl2 catalyst and modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity was dependent on the structure of MMAO, i.e., MMAO-4 exhibited higher catalyst activity than MMAO-3A containing more i-butyl groups. The glass transition temperature (Tg) and the composition of the produced copolymer were not affected by MMAO type. With styrene derivatives as 3rd monomer, Tg of copolymer increased while the catalytic activity decreased. With the addition of 3rd monomer, not only the content of 3rd monomer but also the content of N increased.

AB - The copolymerization of ethylene and norbomene (N) was carried out with iPr(Cp)(FIu)ZrCl2 catalyst and modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity was dependent on the structure of MMAO, i.e., MMAO-4 exhibited higher catalyst activity than MMAO-3A containing more i-butyl groups. The glass transition temperature (Tg) and the composition of the produced copolymer were not affected by MMAO type. With styrene derivatives as 3rd monomer, Tg of copolymer increased while the catalytic activity decreased. With the addition of 3rd monomer, not only the content of 3rd monomer but also the content of N increased.

KW - 3 monomer

KW - Ansa-metallocene catalyst

KW - Copolymerization

KW - Ethylene and norbornene

KW - MMAO cocatalyst

UR - http://www.scopus.com/inward/record.url?scp=38849108137&partnerID=8YFLogxK

U2 - 10.1002/masy.200751405

DO - 10.1002/masy.200751405

M3 - Article

AN - SCOPUS:38849108137

SN - 1022-1360

VL - 260

SP - 27

EP - 33

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Ethylene/norbornene copolymerization with iPr(Cp)(Flu)ZrCl₂ catalyst: Effect of MAO cocatalyst and 3^rd monomer

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this