Fabrication and evaluation of molecularly imprinted structured polymeric films via photopolymerization for bisphenol A detection

Seung Hyo Goo; Ninad B. Velhal; Jinyoung Park

doi:10.1557/s43579-021-00077-1

Fabrication and evaluation of molecularly imprinted structured polymeric films via photopolymerization for bisphenol A detection

Seung Hyo Goo, Ninad B. Velhal, Jinyoung Park

Kyungpook National University

Research output: Contribution to journal › Comment/debate

1 Scopus citations

Abstract

Abstract: Molecularly imprinted polymers (MIPs) are a promising technology for sensing specific analytes. Structured MIP-coated quartz crystal microbalance sensors were developed for the detection of bisphenol A (BPA) using 2-dimethylaminoethyl methacrylate (DMAEMA) as a functional monomer. A simple unidirectional rubbing technique and a soft lithographic technique were used to fabricate convex hemispherical and hierarchical hemispherical MIP patterns, including a planar MIP film as a control. The two structured MIP films exhibited relatively higher imprinting factors and sensitivities compared with the planar MIP film and the selectivity coefficients of the structured MIP films were slightly increased due to the MIP structuring effect. Graphic abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	576-583
Number of pages	8
Journal	MRS Communications
Volume	11
Issue number	5
DOIs	https://doi.org/10.1557/s43579-021-00077-1
State	Published - Oct 2021

Keywords

Adsorption
Hierarchical
Kinetics
Lithography
Polymerization

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10.1557/s43579-021-00077-1

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title = "Fabrication and evaluation of molecularly imprinted structured polymeric films via photopolymerization for bisphenol A detection",

abstract = "Abstract: Molecularly imprinted polymers (MIPs) are a promising technology for sensing specific analytes. Structured MIP-coated quartz crystal microbalance sensors were developed for the detection of bisphenol A (BPA) using 2-dimethylaminoethyl methacrylate (DMAEMA) as a functional monomer. A simple unidirectional rubbing technique and a soft lithographic technique were used to fabricate convex hemispherical and hierarchical hemispherical MIP patterns, including a planar MIP film as a control. The two structured MIP films exhibited relatively higher imprinting factors and sensitivities compared with the planar MIP film and the selectivity coefficients of the structured MIP films were slightly increased due to the MIP structuring effect. Graphic abstract: [Figure not available: see fulltext.]",

keywords = "Adsorption, Hierarchical, Kinetics, Lithography, Polymerization",

author = "Goo, {Seung Hyo} and Velhal, {Ninad B.} and Jinyoung Park",

note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to The Materials Research Society.",

year = "2021",

month = oct,

doi = "10.1557/s43579-021-00077-1",

language = "English",

volume = "11",

pages = "576--583",

journal = "MRS Communications",

issn = "2159-6859",

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TY - JOUR

T1 - Fabrication and evaluation of molecularly imprinted structured polymeric films via photopolymerization for bisphenol A detection

AU - Goo, Seung Hyo

AU - Velhal, Ninad B.

AU - Park, Jinyoung

PY - 2021/10

Y1 - 2021/10

N2 - Abstract: Molecularly imprinted polymers (MIPs) are a promising technology for sensing specific analytes. Structured MIP-coated quartz crystal microbalance sensors were developed for the detection of bisphenol A (BPA) using 2-dimethylaminoethyl methacrylate (DMAEMA) as a functional monomer. A simple unidirectional rubbing technique and a soft lithographic technique were used to fabricate convex hemispherical and hierarchical hemispherical MIP patterns, including a planar MIP film as a control. The two structured MIP films exhibited relatively higher imprinting factors and sensitivities compared with the planar MIP film and the selectivity coefficients of the structured MIP films were slightly increased due to the MIP structuring effect. Graphic abstract: [Figure not available: see fulltext.]

AB - Abstract: Molecularly imprinted polymers (MIPs) are a promising technology for sensing specific analytes. Structured MIP-coated quartz crystal microbalance sensors were developed for the detection of bisphenol A (BPA) using 2-dimethylaminoethyl methacrylate (DMAEMA) as a functional monomer. A simple unidirectional rubbing technique and a soft lithographic technique were used to fabricate convex hemispherical and hierarchical hemispherical MIP patterns, including a planar MIP film as a control. The two structured MIP films exhibited relatively higher imprinting factors and sensitivities compared with the planar MIP film and the selectivity coefficients of the structured MIP films were slightly increased due to the MIP structuring effect. Graphic abstract: [Figure not available: see fulltext.]

KW - Adsorption

KW - Hierarchical

KW - Kinetics

KW - Lithography

KW - Polymerization

UR - http://www.scopus.com/inward/record.url?scp=85114460393&partnerID=8YFLogxK

U2 - 10.1557/s43579-021-00077-1

DO - 10.1557/s43579-021-00077-1

M3 - Comment/debate

AN - SCOPUS:85114460393

SN - 2159-6859

VL - 11

SP - 576

EP - 583

JO - MRS Communications

JF - MRS Communications

IS - 5

ER -

Fabrication and evaluation of molecularly imprinted structured polymeric films via photopolymerization for bisphenol A detection

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Keywords

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